Abstract
Pulse radiolysis of deaerated aqueous solutions of 4·10−5–2.4·10−3 mol dm−3 Triton X-100 gives rise to a transient species originating from the reactions of OH radicals and H atoms. The rate constants of these reactions were found to be 8.8·109 mol−1·dm3·s−1 and 1.25·109 mol−1·dm3·s−1, respectively, for Triton X-100 concentrations below CMC. The corresponding transient species were found to decay according to second order kinetics. The mechanism of the reactions involved including concentration effects is discussed.
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Perkowski, J., Mayer, J. Pulse radiolysis of Triton X-100 aqueous solution. Journal of Radioanalytical and Nuclear Chemistry, Articles 141, 271–277 (1990). https://doi.org/10.1007/BF02035794
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DOI: https://doi.org/10.1007/BF02035794