Abstract
The effect of added TBP on the extraction of uranium(VI) with a solution of di-(2-ethylhexyl)-phosphoric acid (HDEHP) in o-dichlorobenzene from nitric acid solutions has been investigated at varying concentrations of nitric acid, HDEHP, TBP and uranium(VI). The mechanism of the synergistic effect of TBP is discussed on the basis of the results and can be summarized in the following equation: UO 2+2(aq) +0.67(HX)3(o)+2TBP(o)⇆UO2X2·2TBP(o)+2H +(aq) where HX denotes HDEHP and the HDEHP loaded on the foam is trimerized.
Similar content being viewed by others
References
T. BRAUN, A. B. FARAG, Talanta, 19 (1972) 825.
T. BRAUN, A. B. FARAG, Talanta, 22 (1975) 699.
T. BRAUN, A. B. FARAG, in Extraction Chromatography, T. BRAUN, G. GHERSINI (Eds), Elsevier, Amsterdam, 1975.
T. BRAUN, A. B. FARAG, Anal. Chim. Acta, 99 (1978) 1.
T. BRAUN, Cellular Polymers, 3 (1984) 81.
T. BRAUN, J. D. NAVRATIL, A. B. FARAG, Polyurethane Foam Sorbents, CRC Press Inc., 2000 Corporate Blvd., N. W. Boca Raton, Florida, 1985.
S. PALAGYI, T. BRAUN, Report Consultants' Meeting on Nuclear Techniques for Analysis of Environmental Samples, Karlsruhe, Federal Republic of Germany, Feb. 19–21 (1986), IAEA/RL/135, Vienna, Dec. 1986.
T. BRAUN, Fresen. Z. Anal. Chem., 333 (1989) 785.
M. AZIZ, Sh. G. BEHEIR, K. SHAKIR, J. Radioanal. Nucl. Chem., 157 (1992) 105.
K. SHAKIR, M. AZIZ, Sh. G. BEHEIR, J. Radioanal. Nucl. Chem., 147 (1991) 297.
D. F. PEPPARD, J. DRISCOLL, R. J. SIRONEN, S. McCARTY, J. Inorg. Nucl. Chem., 4 (1957) 326.
A. I. VOGEL, A Textbook of Quantitative Inorganic Analysis, 2nd ed., Longmans, London, 1953, p. 470.
K. BHATTACHARYYA, T. K. S. MURTHY, Anal. Chim. Acta, 76 (1975) 91.
A. A. MEMODRUCK, Jr., L. P. GLUKHOV, J. Anal. Chem. USSR, 18 (1963) 85.
F. A. CENTANNI, A. M. ROSS, M. A. DESESA, Anal. Chem., 28 (1956) 1651.
C. A. BLAKE, Jr., C. F. BAES, Jr., K. B. BROWN, C. F. COLEMAN, J. C. WHITE, Proc. of the 2nd Intern. Conf. on the Peaceful Uses of Atomic Energy, Geneva, 1958, Vol. 28, United Nations, 1958, p. 29.
M. ZANGEN, J. Inorg. Nucl. Chem., 25 (1963) 581.
H. IRVING, D. N. EDINGTON, J. Inorg. Nucl. Chem., 15 (1960) 158.
C. J. HARDY, D. SCARGILL, J. Inorg. Nucl. Chem., 11 (1959) 128.
H. T. BAKER, C. F. BAES, Jr., Report ORNL-CF-58-5-93, 1958.
D. DYRSSEN, L. D. HAY, Acta Chem. Scand., 14 (1960) 109.
C. A. BLAKE, D. F. HORNER, J. M. SCHMITT, Report ORNL-2259, 1959.
D. DYRSSEN, L. KUCA, Acta Chem. Scand., 14 (1960) 1945.
J. KENNEDY, Report AERE/C/M-369, 1958.
A. M. DEANE, J. KENNEDY, P. G. SAMMES, Chem. Ind., 443 (1960).
J. KENNEDY, A. M. DEANE, J. Inorg. Nucl. Chem., 19 (1961) 142.
T. SATO, J. Inorg. Nucl. Chem., 26 (1964) 311.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Shakir, K., Beheir, S.G. & Aziz, M. Extraction of certain actinide and lanthanide elements from different acid media by polyurethane foams loaded with di-(2-ethylhexyl)phosphoric acid (HDEHP). Journal of Radioanalytical and Nuclear Chemistry, Articles 162, 371–380 (1992). https://doi.org/10.1007/BF02035397
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02035397