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Mössbauer study of sodium ferrates(IV) and (VI)

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Abstract

Sodium ferrates(IV) and (VI) were synthesized by the reaction between Fe2O3 and Na2O2 in a dry oxygen stream. The Mössbauer data for the obtained samples are presented (for Na2FeO3−δ=0.18(2) mm/s; for Na4FeO5−δ=−0.54(2) mm/s). It was shown that pure K2FeO4 and Cs2FeO4 can be obtained by heating Fe2O3 with apropriate alkali metal peroxides.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 119899, Moscow, (Russia)

    N. S. Kopelev, Yu. D. Perfiliev & Yu. M. Kiselev

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  1. N. S. Kopelev
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  2. Yu. D. Perfiliev
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  3. Yu. M. Kiselev
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Kopelev, N.S., Perfiliev, Y.D. & Kiselev, Y.M. Mössbauer study of sodium ferrates(IV) and (VI). Journal of Radioanalytical and Nuclear Chemistry, Articles 162, 239–251 (1992). https://doi.org/10.1007/BF02035384

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