Abstract
151Sn Mössbauer spectroscopy was performed with tin triflate Sn(OTf)2 in order to determine its Mösbauer parameters for analytical purposes. The typical Mössbauer parameters at 80 K for crystalline Sn(OTf)2 are IS=4.01±0.02 mm/s and QS=1.20±0.04 mm/s and show that the stannous ion is at a site with less than cubic symmetry under perturbation of the crystal field effect.
References
J. G. Stevens, (Ed.), Mössbauer Data and Reference Journal, Ashville, 1965.
A. Vértes, K. Burger, L. Korecz, Mössbauer Spectroscopy, Elsevier-Akadémiai Kiadó, Budapest, Amsterdam, 1979.
T. H. Tan, J. R. Dalziel, P. A. Yeats, J. R. Sam, R. C. Thompson, F. Aubke, Can. J. Chem., 50 (1972) 1843.
Z. Klencsár, E. Kuzmann, A. Vértes, J. Radioanal. Nucl. Chem., 120 (1996) 105.
P. A. Flinn, in: Mössbauer Isomer Shifts,G. K. Shenoy andF. E. Wagner (Eds), North Holland, 1978, p. 593. and references therein.
J. D. Donaldson, D. C. Puxley, M. J. Tricker, Inorg. Nucl. Chem. Lett., 8 (1972) 845.
T. Kégl, Szalontay, L. Kollár, E. Kuzmann, A. Vértes, J. Org. Met. Chem., 507 (1996) 75.
T. Kégl, L. Kollár, E. Kuzmann, A. Vértes, publication in preparation.
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Kuzmann, E., Kégl, T., Kollár, L. et al. Mössbauer characterization of tin triflate Sn(OTf)2 . J Radioanal Nucl Chem 220, 103–104 (1997). https://doi.org/10.1007/BF02035357
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DOI: https://doi.org/10.1007/BF02035357