Journal of Radioanalytical and Nuclear Chemistry

, Volume 150, Issue 2, pp 435–444 | Cite as

Precision of a plutonium analytical method using solvent extraction and spectrophotometry

  • P. G. MendozaJr.
  • D. D. Jackson
  • T. M. Niemczyk
Article
  • 28 Downloads

Abstract

We investigated the plutonium assay method that uses the plutonyl trinitrate tetrapropyl-ammonium ion-pair solvent extraction with spectrophotometry of the extract as a candidate method capable of providing robustness and precision. To identify and assess the effect of factors on the precision, we looked at sampling techniques, silver oxide oxidation conditions extraction time, extract stability, and temperature dependence of the extract analytical peak height and position. We obtained a precision of 0.12%.

Keywords

Oxidation Inorganic Chemistry Oxidation Condition Solvent Extraction Peak Height 

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Copyright information

© Akadémiai Kiadó 1991

Authors and Affiliations

  • P. G. MendozaJr.
    • 1
  • D. D. Jackson
    • 1
  • T. M. Niemczyk
    • 2
  1. 1.Chemical and Laser Sciences DivisionLos Alamos National LaboratoryLos Alamos(USA)
  2. 2.Department of ChemistryUniversity of New MexicoAlbuquerque(USA)

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