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Carbon-13 intermolecular isotope effect in the decarbonylation of liquid extra pure Merck formic acid

  • M. Zieliński
  • A. Zielińska
  • S. Bernasconi
  • H. Papiernik-Zielińska
Letter to the Editor

Abstract

Intemolecular13C isotope effects in the decarbonylation of extra pure Merck liquid formic acid have been determined in the temperature interval 50–100 °C and compared to13C KIE observed in the decomposition of 99.9% liquid formic acid in the temperature range 60–100 °C. A very constants in the Arrhenius and Eyring equations have been calculated and found to be in a good agreement with the corresponding values ofBarham andClark.8

Keywords

Physical Chemistry Inorganic Chemistry Formic Acid Temperature Interval Isotope Effect 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Akadémiai Kiadó 1997

Authors and Affiliations

  • M. Zieliński
    • 1
  • A. Zielińska
    • 1
  • S. Bernasconi
    • 2
  • H. Papiernik-Zielińska
    • 1
  1. 1.Isotope Laboratory (Laboratory of Nuclear Chemistry), Faculty of ChemistryJagiellonian UniversityKrakówPoland
  2. 2.Laboratory of Stable Isotopes (Geologisches Institut)ETH (Swiss Federal Institute of Technology), ZürichZürichSwitzerland

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