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Fixation and reduction of molecular nitrogen by [WH4(PC2H5Ph2)4] and [WH4(PCH3Ph2)4] in a γ-radiation field

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Abstract

Hydride complexes of W(IV) with dpep (diphenylethylphosphine) and dpmp (diphenylmethylphosphine) were irradiated in thf+C6H12(1∶1) solutions, saturated with N2+H2(1∶3). Radiation yields of hydrazine, ammonia and amines were evaluated. The mechanism of reduction of molecular nitrogen is discussed.

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Authors and Affiliations

  1. Institute of Chemistry, Silesian University, 9 Szkolna Street, 40-006, Katowice, Poland

    J. O. Dziegielewski, R. Gil-Bortnowska & J. Mrzigod

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  1. J. O. Dziegielewski
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  2. R. Gil-Bortnowska
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  3. J. Mrzigod
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Dziegielewski, J.O., Gil-Bortnowska, R. & Mrzigod, J. Fixation and reduction of molecular nitrogen by [WH4(PC2H5Ph2)4] and [WH4(PCH3Ph2)4] in a γ-radiation field. Journal of Radioanalytical and Nuclear Chemistry, Articles 163, 325–333 (1992). https://doi.org/10.1007/BF02034806

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  • DOI: https://doi.org/10.1007/BF02034806

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