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BISPHENYLENECOSAN as highly selective Cs+ extraction agent

  • P. Selucký
  • N. V. Sistková
  • J. Rais
Article

Abstract

A new reagent for the highly selective extraction of cesium (e-1,7′–2,2′)4,8′–8,4′-(bis-μ-o-phenylene)bisdicarbollidocobalt(1−)ate, [(C2B9H9)2(C6H4)2Co], abbreviated as BISPHECOSAN is described in this paper. The choice of organic solvent and solubilizer, dependence of distribution ratio of Cs+ on acidity and other parameters are studied. The extraction mechanism based on selective binding of Cs+ cation between two phenylene rings is presented and factors influencing the chemical stability of the reagent are determined.

Keywords

Physical Chemistry Inorganic Chemistry Phenylene Acidity Cesium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Akadémiai Kiadó 1997

Authors and Affiliations

  • P. Selucký
    • 1
  • N. V. Sistková
    • 1
  • J. Rais
    • 1
  1. 1.Nuclear Research Institute, plcRežCzech Republic

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