Skip to main content
Log in

Radiometric method for the study of the nucleation of crystals containing134Cs+ ions in gelatin

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

A radiometric method that permits to follow, in real time, the kinetics of crystals growth:134CsClO4;134CsHC4H4O6;134Cs2CrO4;134Cs2[PtCl6] and134Cs[AgI2], in gelatin medium is presented. Constants of the diffusion of134Cs+ radioactive ions through gel and of the reaction between this cation and anions under study, leading to the formation of crystals were calculated. An approximately invesely proportional ratio was found between the rate of nucleation and the solubility of the crystal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. E. Liesegang, Chemische Reaktionen in Gallerten, Steinkopff Verlag, Dresden, 1924.

    Google Scholar 

  2. L. Aschoff, Kolloid Z., 89 (1939) 107.

    Article  Google Scholar 

  3. E. S. Halberstadt, Nature, 216 (1967) 574.

    Google Scholar 

  4. G. K. Kirov, J. Cryst. Growth, 15 (1972) 102.

    Article  Google Scholar 

  5. R. A. Patel, S. K. Arora, J. Cryst. Growth, 18 (1973) 199.

    Article  Google Scholar 

  6. K. M. Pillai, M. A. J. Ittyachen, Current Sci., 98 (1972) 202.

    Google Scholar 

  7. H. K. Henisch, J. M. Garcia-Ruiz, J. Cryst. Growth, 75 (1986) 195.

    Article  Google Scholar 

  8. E. S. Hedges, Liesegang Rings, Chapman, London, 1932.

    Google Scholar 

  9. H. K. Henisch, Crystals in Gels and Liesegang Rings, Cambridge Press, Cambridge, 1988.

    Google Scholar 

  10. A. A. Chernov, Contemporary Phys., 30 (1989) 251.

    Google Scholar 

  11. D. T. J. Hurle, (Ed.) Handbook of Crystal Growth, North-Holland, Amsterdam, 1993.

    Google Scholar 

  12. Al. Cecal, M. Palamaru, A. Spac, J. Radioanal. Nucl. Chem., 176 (1993) 1.

    Google Scholar 

  13. Al. Cecal, M. Palamaru, A. Juverdeanu, R. Giosan, J. Cryst. Growth, 158 (1996) 181.

    Article  Google Scholar 

  14. Al. Cecal, M. Palamaru, D. Humelnicu, Rev. Roumaine Chim. (in press).

  15. R. Ripan, E. Popper, C. Liteanu, Chimie analitica calitativa, Semimicroanaliza, Editura Tehnica, Bucuresti, 1957.

    Google Scholar 

  16. R. Ebisch, E. Fanghänel, W. D. Hobicher, R. Hahn, K. Unverferth, Chemische Kinetik, VEB Deutscher Verlag für Grundstoffindustrie, Leipzig, 1980.

    Google Scholar 

  17. Handbook of Physics and Chemistry, CRC Press, Cleveland, 1976.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cecal, A., Palamaru, M., Pui, A. et al. Radiometric method for the study of the nucleation of crystals containing134Cs+ ions in gelatin. J Radioanal Nucl Chem 222, 39–43 (1997). https://doi.org/10.1007/BF02034244

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02034244

Keywords

Navigation