Abstract
This paper investigates the simultaneous reduction and oxidation reactions of uranium in hydrochloric acid media. The redox reactions were carried out in a cell fitted with a cation exchange membrane and hexavalent uranium was reduced to the tetravalent state in the cathode chamber. The reverse reaction was carried out in the anode side of the cell. The reaction rate was found to be independent of the uranium concentration and the extent of reaction was linear with time. There is evidence of uranium flux across the membrane.
Similar content being viewed by others
References
H. Majima, Y. Awakura, S. Hirono, Metallurgical Transaction B, 17B (1986) 41–50.
Y. Awakura, H. Hiai, H. Majima, S. Hirono, Metall. Trans. B, 20B, 1989, 337–343.
P. Donson, D. A. White andS. Bashir, Hydrometallurgy, 28 (1992) 67–74.
H. G. Heal, Trans. Faraday Soc., 45, 1949, 1–20.
E. S. Kritchevsky, J. C. Hindman, J. Am. Chem. Soc., 71 (1949) 2097.
C. C. Hsiang, C. T. Chang, J. Inorg. Nucl. Chem., 37 (1975) 1949.
D. S. Flett Ellis Horwood Ltd., England, 1983, p. 191.
E. A. Mason, E. J. Parsi, Proc. the 2nd United Nations Internat. Conf. on the Peaceful Uses of Atomic Energy, Geneva, vol. 17, 1958, p. 200.
K. W. Kim. Y. J. Shin, J. H., H. S. Park, J. D. Kim, Proc. ISEC '90, Part A,T. Sekine, (Ed.), 1990, p. 645.
1982.H. Feess, H. Wendt, Ger. Chem. Eng., 5, (1982) 156.
1978 Annual Book of ASTM Standards, American Society for Testing & Materials, 1916 Race St., Philadelphia, Pa., Part 45, 1978, p. 576.
W. Davies, W. Gray, Talanta, 11 (1964) 1203.
Gmelin Handbook of Inorganic Chemistry, 8th ed. U Suppl. Vol. D1, 1984, p. 90.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
White, D.A., Fathurrachman An experimental investigation of uranium redox reactions in an electrolytic cell with a cation exchange membrane. J Radioanal Nucl Chem 218, 27–32 (1997). https://doi.org/10.1007/BF02033969
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02033969