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Mössbauer effect studies on thermal decomposition of iron(III) hydroxy- and amino-benzoates

  • Organic Compounds
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Abstract

The thermal decomposition of iron(III) aminobenzoates (o-, m-, p-) and iron(III) hydroxybenzoates (p-, m-, p-) have been investigated from ambient temperature to 873 K in air using derivatography DTG-DTA-TG, Mössbauer, IR spectroscopy and XRD. The importance of Mössbauer spectra recorded at various stages of heating, without separating the product mixture, in studying the mode of decomposition is highlighted. The intermediates (e.g., Fe(II)-species) were confirmed. The nature of water of hydration and the order of stability (p->m->o-) have been investigated from decomposition temperatures. The kinetic model and parameters have been investigated for dehydration.

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References

  1. P. K. Gallagher and C. R. Kurkjian, Inorg. Chem., 5 (1966) 214.

    Article  CAS  Google Scholar 

  2. G. G. Hawley, The Condensed Chemical Dictionary, 8th edn., Van Nost. Reim. Co., New York 1971.

    Google Scholar 

  3. R. L. Cohen (ed.), Applications of Mössbauer Spectroscopy, Vol. I, Academic Press, New York 1976.

    Google Scholar 

  4. P. S. Bassi, B. S. Randhawa and H. S. Jamwal, Thermochim. Acta, 62 (1983) 209.

    Article  CAS  Google Scholar 

  5. P. S. Bassi, B. S. Randhawa and H. S. Jamwal, Thermochim. Acta, 65 (1983) 1.

    Article  CAS  Google Scholar 

  6. P. S. Bassi, B. S. Randhawa and G. K. Bilaspuri, J. Thermal Anal., 31 (1986) 1007.

    Article  CAS  Google Scholar 

  7. D. L. Dinsel and T. R. Sweet, Anal. Chem., 35 (1963) 2077.

    Article  CAS  Google Scholar 

  8. Y. Takashima and T. Tateishim, Bull. Chem. Soc. Japan, 38 (1965) 1688.

    Article  CAS  Google Scholar 

  9. I. A. Vogel, Vogel's Text book of Quantitative Inorganic Analysis including Elementary Instrumental Analysis. Longman Group Ltd., London 1982, p. 742.

    Google Scholar 

  10. J. Inczedy, Analytical Application of Ion Exchange, Pergamon Press, Oxford 1966, p. 81.

    Google Scholar 

  11. K. Mahesh, N. D. Sharma, D. C. Gupta and D. M. Puri, Proc. Ind. Natl. Sci. Acad. Part A, 45 (1979) 277.

    CAS  Google Scholar 

  12. G. I. Brown, A New Guide to Modern Valency Theory Longmans, Green & Co. Ltd. London 1967, p. 183.

    Google Scholar 

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Authors and Affiliations

  1. Chemistry Department, Guru Nanak Dev University, 143 005, Amritsar, India

    P. S. Bassi, Punam Uppal & G. K. Bilaspuri

Authors
  1. P. S. Bassi
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  2. Punam Uppal
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  3. G. K. Bilaspuri
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Additional information

P.U. and G.K.B. thank to Guru Nanak Dev. University, Amritsar for financial assistance.

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Bassi, P.S., Uppal, P. & Bilaspuri, G.K. Mössbauer effect studies on thermal decomposition of iron(III) hydroxy- and amino-benzoates. Journal of Thermal Analysis 49, 703–711 (1997). https://doi.org/10.1007/BF01996754

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  • DOI: https://doi.org/10.1007/BF01996754

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