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Möglichkeiten der adiabatischen Präzisionskalorimetrie zur Kinetikaufklärung

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Abstract

The investigation of the hazardous potential of reaction courses is very important for the chemical industry. Compared with the isoperibolic the adiabatic calorimetry has essential advantages for kinetic evaluations, because corrections of heat flux are not necessary. With the adiabatic precision calorimeter ACTRON 5 is the investigation of reaction courses in small volumes possible. The possibilities of the nonlinear investigation program TA-kin are shown with examples of Semi-Batch-Measurements. With this program the change in heat capacities whilst encoring the second component is included.

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Literatur

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Authors and Affiliations

  1. Institut für Physikalische Chemie, Universität Greifswald, Soldtmannstr. 23, D-17489, Greifswald, Deutschland

    K. Heldt & H. L. Anderson

Authors
  1. K. Heldt
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  2. H. L. Anderson
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Professor Hans-Joachim Seifert zum 65. Geburtstage gewidmet

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Heldt, K., Anderson, H.L. Möglichkeiten der adiabatischen Präzisionskalorimetrie zur Kinetikaufklärung. Journal of Thermal Analysis 47, 559–567 (1996). https://doi.org/10.1007/BF01983997

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  • DOI: https://doi.org/10.1007/BF01983997

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