Skip to main content
SpringerLink
Log in

Thermal dissociation of basic aluminium-ammonium sulfate in an atmosphere of hydrogen and carbon monoxide

  • Inorganic Compounds
  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

A study was made of the effect of an atmosphere of H2+CO (a 3∶1 molar mixture) on the mechanism and the kinetics of desulfuration of basic aluminium-ammonium sulfate under variable pressures of hydrogen and carbon monoxide. The temperature region of the process, the nature of almost all the solid intermediates, and the equations and kinetic parameters relating to the rate of desulfurization of the compound for α<0.6 were determined. Despite the complexity of the process, the results permitted determination of the temperature and the composition of the gas phase necessary for the process of desulfuration to occur and for aluminium oxides with the required properties to be obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. B. Pacewska and J. Pysiak, Thermochim. Acta, 179 (1991) 187.

    Article  CAS  Google Scholar 

  2. B. Pacewska and J. Pysiak, J. Thermal Anal., 37 (1991) 1665.

    Article  CAS  Google Scholar 

  3. B. Pacewska, J. Thermal. Anal., 36 (1990) 2021.

    Article  CAS  Google Scholar 

  4. B. Pacewska and J. Pysiak, J. Thermal Anal., 37 (1991) 1389.

    Article  CAS  Google Scholar 

  5. B. Pacewska and J. Pysiak, J. Thermal Anal., 33 (1988) 511.

    Article  Google Scholar 

  6. B. Pacewska, Thermochim. Acta, 208 (1992) 167.

    Article  Google Scholar 

  7. B. Pacewska, Thermochim. Acta, 200 (1992) 387.

    Article  CAS  Google Scholar 

  8. B. Pacewska, T. Zmijewski and M. Mioduska, J. Thermal Anal., 43 (1995) 103.

    Article  CAS  Google Scholar 

  9. T. Zmijewski, B. Pacewska and J. Pysiak, J. Thermal Anal., 43 (1995) 113.

    Article  CAS  Google Scholar 

  10. B. Pacewska, Thermochim Acta, in press.

  11. C. Rózycki and M. Maciejewski, Thermochim. Acta, 96 (1985) 91.

    Article  Google Scholar 

  12. C. Rózycki and M. Maciejewski, Thermochim Acta, 122 (1987) 339.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Plock Branch of Warsaw University of Technology, Lukasiewicza 17, 09-400, Plock, Poland

    T. Zmijewski & B. Pacewska

Authors
  1. T. Zmijewski
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. Pacewska
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

The authors would like to express their thanks to Prof. Janusz Pysiak for valuable discussions.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zmijewski, T., Pacewska, B. Thermal dissociation of basic aluminium-ammonium sulfate in an atmosphere of hydrogen and carbon monoxide. Journal of Thermal Analysis 49, 1187–1195 (1997). https://doi.org/10.1007/BF01983674

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01983674

Keywords

Search

Navigation