Journal of thermal analysis

, Volume 46, Issue 3–4, pp 1081–1092 | Cite as

Thermal properties of a molecule in a constrained state

Dye-amylose inclusion complex
  • Suk -Fai Lau
  • A. J. Sosnowik
  • Ling -Siu Choi
  • J. H. Callahan
  • Oh -Kil Kim
Article

Abstract

The thermal properties of a dye molecule (guest) inside the cavity of a host amylose helix were studied by TGA, DSC, and Thermal Desorption MS. The results show that the degradation temperature of dye shifts to a higher temperature by approximately 20°C.

Keywords

chemical ionization MS constrained dye DSC dye-amylose inclusion complex Tandem MS TGA Thermal Desorption MS 

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References

  1. 1.
    J. M. Lehn, Angew. Chem. Int. Ed. Engl., 29 (1990) 1304.CrossRefGoogle Scholar
  2. 2.
    J. Szejtli, “Cyclodextrin Technology”, Kluwer Academic Publishers, Netherlands 1988.Google Scholar
  3. 3.
    R. J. Bergeron in “Inclusion Compounds”, Vol. 3 (ed. J. L. Atwood, J. E. D. Davies and D. D. MacNicol), Academic Press, New York 1984, pp. 391–443.Google Scholar
  4. 4.
    J. Szejtli, ibid., pp. 331–390.Google Scholar
  5. 5.
    W. Saenger, Angew. Chem., Int. Ed. Engl., 19 (1980) 344.Google Scholar
  6. 6.
    G. Wenz, ibid., 33 (1994) 803.Google Scholar
  7. 7.
    A. Harada, J. Li and M. Kamachi, Nature, 356 (1992) 325.CrossRefGoogle Scholar
  8. 8.
    Y. Yamashita, J. Polym. Sci. part A, 3 (1965) 3251.CrossRefGoogle Scholar
  9. 9.
    Y. Yamashita and N. Hirai, J. Polym. Sci., Polym. Phys. Ed., 4 (1966) 161.Google Scholar
  10. 10.
    Y. Yamashita and K. Monobe, J. Polym. Sci., Polym. Phys. Ed., 9 (1971) 1471.Google Scholar
  11. 11.
    H. Nakatani, K.-I. Shibata, H. Kondo and K. Hiromi, Biopolymers, 16 (1977) 2363.CrossRefGoogle Scholar
  12. 12.
    T. Kuge and K. Takeo, Agr. Biol. Chem., 32 (1968) 1232.Google Scholar
  13. 13.
    G. Wulff and S. Kubik, Makromol. Chem., 193 (1992) 1071.CrossRefGoogle Scholar
  14. 14.
    Y. Hui, X. Cheng, J. Gu and X. Jiang, Scientia Sinica (Series B), 25 (1982) 698.Google Scholar
  15. 15.
    Y. Hui, J. C. Russell and D. G. Whitten, J. Am. Chem. Soc., 105 (1983) 1374.CrossRefGoogle Scholar
  16. 16.
    B. R. Suddaby, R. N. Dominey, Y. Hui and D. G. Whitten, Can. J. Chem., 63 (1985) 1315.Google Scholar
  17. 17.
    M. T. Allen, L. Miola, B. R. Suddaby and D. G. Whitten, Tetrahedron, 43 (1987) 1477.CrossRefGoogle Scholar
  18. 18.
    O.-K. Kim and L. S. Choi, Langmuir, 10 (1994) 2842.CrossRefGoogle Scholar
  19. 19.
    J. Szejtli and E. Bola, Starch, 32 (1980) 386.Google Scholar

Copyright information

© Akadémiai Kiadó 1996

Authors and Affiliations

  • Suk -Fai Lau
    • 1
  • A. J. Sosnowik
    • 1
  • Ling -Siu Choi
    • 1
    • 2
  • J. H. Callahan
    • 1
    • 2
  • Oh -Kil Kim
    • 2
  1. 1.Research CenterHercules IncorporatedWilmington
  2. 2.Chemistry DivisionNaval Research LaboratoryWashington, DCUSA

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