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Oxygen exchange study in phase transformations of superconducting bismuth cuprates (Pb2212 and Pb2223)

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Abstract

The oxygen exchange between the condensed phase(s) and the gas phase was studied as a function of temperature for superconducting phases of the system (Bi,Pb)-Sr-Ca-Cu-O.

An oxygen probe apparatus allowed confirmation that the variation in oxygen composition in the Pb2212 and Pb2223 superconducting phases is a reversible phenomenon on heating and cooling. It was demonstrated that the mass loss of both phases, for the 905 and 980°C isotherms, was due to the oxygen composition variation and to PbO loss (this latter phenomenon begin irreversible).

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Authors and Affiliations

  1. Laboratoire de Physico-Chimie du Matériau et du Milieu Marin, Matériaux à Finalité Spécifique (E.A. 1356), Faculté des Sciences et Techniques, Université de Toulon et du Var, B.P. 132, 83957, La Garde Cedex, France

    M. Mansori, C. Favotto, K. Jardet, M. Roubin, A. Sebaoun & P. Satre

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  1. M. Mansori
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  2. C. Favotto
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  3. K. Jardet
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  4. M. Roubin
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  5. A. Sebaoun
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  6. P. Satre
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Mansori, M., Favotto, C., Jardet, K. et al. Oxygen exchange study in phase transformations of superconducting bismuth cuprates (Pb2212 and Pb2223). Journal of Thermal Analysis 50, 401–407 (1997). https://doi.org/10.1007/BF01980500

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  • DOI: https://doi.org/10.1007/BF01980500

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