Advertisement

Journal of thermal analysis

, Volume 46, Issue 1, pp 327–330 | Cite as

Thermal studies of some aryloxides of titanium(IV)

  • K. C. Malhotra
  • N. Sharma
  • S. S. Bhatt
  • S. C. Chaudhry
Short Communications

Abstract

Thermal behaviour of aryloxides of titanium(IV) of composition TiCln(OAr)4−n (wheren=0→3 and OAr=OC6But-4, OC6H4OMe-4 and OC6H2-Bu 2 t -2,6−Me-4) has been studied by DTA and TG analysis. Multiple decomposition steps have been indicated by thermal weight losses which are both exothermic and endothermic as shown by DTA curves. Based upon the total % loss in weight; during entire decomposition titanium dioxide has been found to be the final residue in each case.

Keywords

aryloxides titanium 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    G. R. Clark, A. J. Nielson and C. F. F. Richard, Polyhedron, 6 (1987) 1765.CrossRefGoogle Scholar
  2. 2.
    R. W. Chesnut, B. D. Steffy and I. P. Rothwell, Polyhedron, 8 (1989) 1607.CrossRefGoogle Scholar
  3. 3.
    L. R. Chamberlain and I. P. Rothwell, J. Am. Chem. Soc., 105 (1983) 1965.CrossRefGoogle Scholar
  4. 4.
    L. R. Chamberlain, J. L. Kerschner, A. P. Rothwell, I. P. Rothwell and J. C. Huffman, J. Am. Chem. Soc., 109 (1987) 6471.CrossRefGoogle Scholar
  5. 5.
    G. Pfeifer and T. Flora, Magyar Kém. Folyóirat, 70 (1964) 375.Google Scholar
  6. 6.
    K. C. Malhotra, Neeraj Sharma, S. S. Bhatt and S. C. Chaudhry, J. Ind. Chem. Soc., 67 (1990) 830.Google Scholar
  7. 7.
    S. C. Chaudhry, A. Kumar, S. S. Bhatt and N. Sharma, Synth. React. Inorg. Met-Org. Chem., 22 (1992) 1.Google Scholar
  8. 8.
    K. C. Malhotra, N. Sharma, S. S. Bhatt and S. C. Chaudhry, Polyhedron, 11 (1992) 2065.CrossRefGoogle Scholar
  9. 9.
    F. Fischer and U. Ehrhardt, Ges. Abhandl. Kenninis Kohle, 4 (1919) 237; CA. 15 (1921) 3635.Google Scholar
  10. 10.
    S. C. Chaudhry and S. Mehta, Curr. Science, 53 (1984) 406.Google Scholar

Copyright information

© Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest 1996

Authors and Affiliations

  • K. C. Malhotra
    • 1
  • N. Sharma
    • 1
  • S. S. Bhatt
    • 1
  • S. C. Chaudhry
    • 1
  1. 1.Department of ChemistryHimachal Pradesh UniversityShimlaIndia

Personalised recommendations