Journal of thermal analysis

, Volume 46, Issue 1, pp 205–210 | Cite as

Etude des equilibres solide-liquide du systeme pseudo-binaire LiPO3-RbPO3

  • O. S. M. Elmokhtar
  • M. Rzaigui
Article

Abstract

The LiPO3-RbPO3 system was investigated by differential thermal analysis, X-ray diffraction and infrared spectroscopy. The system forms two linear polyphosphate compounds: Li2Rb(PO3)3 and LiRb(PO3)2. The first one melts in a peritectic reaction at 552°C and the second one melts congruently at 613°C. It is established that both compounds are mixed polyphosphates with chain structure. Their reticular distances and IR characteristics are given here.

Keywords

DTA IR LiPO3-RbPO3 system X-ray 

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Copyright information

© Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest 1996

Authors and Affiliations

  • O. S. M. Elmokhtar
    • 1
  • M. Rzaigui
    • 1
  1. 1.Faculté des SciencesLaboratoire de Chimie des MatériauxZarzouna, BizerteTunisie

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