Skip to main content
SpringerLink
Log in

Thermal, spectral and magnetic studies on glycine complexes of cobalt(II), nickel(II) and zinc(II) with hydrazine

  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

Hydrazinium metal glycinates [(N2H5 2M(NH2CH2COO)4] and bis(hydrazine)metal glycinates, [M(NH2CH2COO)2(N2H4)2], whereM=Co, Ni or Zn have been prepared and characterized by chemical analyses, magnetic moments and vibrational and electronic spectra. The thermal behaviour of these compounds has been studied by thermogravimetry and differential thermal analyses. These complexes decompose with high exothermicity giving metal powder as the final residue. The X-ray powder data of each set of complexes show isomorphism among themselves.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Comprehensive Coordination Chemistry — The Synthesis, Reactions, Properties and Applications of Coordination Compounds, Edited by G. Wilkinson, R. D. Gillard, J. A. McCleverty, Vol. II, Pergamon Press, London 1987, p. 740.

    Google Scholar 

  2. T. J. Lane, J. A. Durkin and R. J. Hooper, Spectrochim. Acta, 20 (1964) 1013.

    Article  Google Scholar 

  3. R. A. Condrate and K. Nakamoto, J. Chem. Phys., 42 (1964) 2590.

    Article  Google Scholar 

  4. B. W. Low, F. L. Hirshfeld and F. M. Richards, J. Am. Chem. Soc., 81 (1959) 4412.

    Article  Google Scholar 

  5. D. N. Sen, S. Mizushima, C. Curren and J. V. Quaglians, J. Am. Chem. Soc., 77 (1955) 211.

    Article  Google Scholar 

  6. G. Schwarzenbach, R. Gut and G. Ander, Helv. Chim. Acta, 37 (1954) 937.

    Article  Google Scholar 

  7. C. F. Campana, D. F. Shepard and W. M. Litchman, Inorg. Chem., 20 (1981) 4039.

    Article  Google Scholar 

  8. D. Gajapathy, S. Govindarajan, K. C. Patil and H. Manohar, Polyhedron, 2 (1983) 865.

    Article  Google Scholar 

  9. K. C. Patil, D. Gajapathy and K. Kishore, Thermochim. Acta, 52 (1982) 113.

    Article  Google Scholar 

  10. P. Ravindranathan and K. C. Patil, Thermochim. Acta, 71 (1983) 53.

    Article  Google Scholar 

  11. G. V. Mahesh and K. C. Patil, Thermochim. Acta, 99 (1986) 188.

    Google Scholar 

  12. K. C. Patil, R. Soundararajan and E. P. Goldberg, Synth. React. Inorg. Met.-Org. Chem., 13 (1983) 29.

    Google Scholar 

  13. A. Braibanti, G. Bigliardi, A. M. Manotti Lanfredi and A. Tiripicchio, Nature, 211 (1966) 1174.

    Google Scholar 

  14. P. Ravindranathan and K. C. Patil, Proc. Indian Acad. Sci. (Chem. Sci.), 95 (1985) 345.

    Google Scholar 

  15. J. Macek and A. Rahten, Thermochim. Acta, 144 (1989) 257.

    Article  Google Scholar 

  16. I. A. Vogel, A Textbook of Quantitative Inorganic Analysis, 2nd Ed. Longmans London, 1951.

    Google Scholar 

  17. B. N. Figgis and J. Lewis, J. Prog. Inorg. Chem., 6 (1964) 197.

    Google Scholar 

  18. A. B. P. Lever, Inorganic Electronic Spectroscopy, 2nd Ed. Elsevier, Amsterdam 1984.

    Google Scholar 

  19. A. Braibanti, F. Dallavalle, M. A. Pellinghelli and E. Leporati, Inorg. Chem., 7 (1968) 1430.

    Article  Google Scholar 

  20. J. Macek, R. Hrovat and B. Novosel, J. Thermal Anal., 40 (1993) 335.

    Google Scholar 

  21. B. N. Sivasankar and S. Govindarajan, Thermochim. Acta, 244 (1994) 235.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Bharathiar University, 641 046, Coimbatore, India

    B. N. Sivasankar & S. Govindarajan

Authors
  1. B. N. Sivasankar
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Govindarajan
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sivasankar, B.N., Govindarajan, S. Thermal, spectral and magnetic studies on glycine complexes of cobalt(II), nickel(II) and zinc(II) with hydrazine. Journal of Thermal Analysis 46, 117–127 (1996). https://doi.org/10.1007/BF01979952

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01979952

Keywords

Search

Navigation