Journal of thermal analysis

, Volume 46, Issue 5, pp 1403–1412 | Cite as

Thermoanalytical study of some salts of3d metals withd-tartaric acid

  • I. Dranca
  • T. Lupaşcu
  • V. Sofransky
  • V. Popa
  • M. Voss
Article

Abstract

The processes of dehydration and decomposition of the Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) salts ofd-tartaric acid were studied by using TG, DTG and DTA methods in air or in argon, and also IR-spectroscopy.

The equations of thermal decomposition were established. For the dehydration processes, the kinetic parametersn, E andInA were determined.

Keywords

d-tartaric acid salts 3d metals IR spectra thermal analysis 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    A. V. Ablov and G. A. Popovici, Zh. Obshch. Khim., 24 (1954) 974.Google Scholar
  2. 2.
    I. M. Ciurokova, D. N. Glebivskii and A. S. Kreiciuk, Vestnik Leningrad. Univ., 4 (1986) 126.Google Scholar
  3. 3.
    I. Drancă, T. Lupascu, V. Sofranski, V. Ropot and I. Haritonov, Zh. Neorg. Khim., (in press).Google Scholar
  4. 4.
    S. Kirschner and R. Kiesling, J. Amer. Chem. Soc., 82 (1960) 4174.CrossRefGoogle Scholar
  5. 5.
    D. I. Alioshin, L. S. Soloviev and A. L. Iudin, Izv. Sib. Otd. A. N. SSSR, Ser. Khim. Nauk., 9 (1967) 11.Google Scholar
  6. 6.
    V. Ropot, A. Maftuleac, V. Sofranskii and I. Drancă, Zh. Fiz. Khim., 61 (1983) 1988.Google Scholar
  7. 7.
    K. Nakamoto, Infrared and Raman Spectra of Inorganic Compounds (Russian translation), Mir. Moskova 1991, p. 257.Google Scholar
  8. 7a.
    L. Belami ‘Novie dannie po IK spectram slojnih molekul’, Mir. Moskova 1971, p. 318.Google Scholar
  9. 8.
    K. I. Pribilov, R. I. Valiukina and R. A. Gorodnicheva, Zh. Neorg. Khim., 30 (1985) 2698.Google Scholar
  10. 9.
    K. I. Pribilov, R. I. Valiukina and R. A. Gorodnicheva, Zh. Neorg. Khim., 32 (1987) 2198.Google Scholar
  11. 10.
    V. A. Klimova, Osnovnie Micrometodi Analiza Organiceskih Soedinenii, Himia, Moskova 1975, p. 59.Google Scholar
  12. 10a.
    C. Sharlo ‘Metody analiticeskoi himii’. (in Russian) Himia, Moskova 1965, p. 975.Google Scholar
  13. 11.
    I. Paulik, F. Paulik and M. Arnold, J. Thermal Anal., 32 (1987) 301; M. Arnold, P. Somogyvári, J. Paulik and F. Paulik, J. Thermal Anal., 32 (1987) 679.CrossRefGoogle Scholar
  14. 12.
    M. C. Puerta and P. Valerga, J. Chem. Education, 67 (1990) 344.Google Scholar

Copyright information

© Akadémiai Kiadó 1996

Authors and Affiliations

  • I. Dranca
    • 1
  • T. Lupaşcu
    • 1
  • V. Sofransky
    • 1
  • V. Popa
    • 2
  • M. Voss
    • 2
  1. 1.Institute of Chemistry of the Moldova Academy of SciencesChisinauRepublic of Moldova
  2. 2.Institute of Physical ChemistryRomanian AcademyBucharestRomania

Personalised recommendations