Skip to main content
SpringerLink
Log in

About the thermal decomposition of tetracyanocomplexes

  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

Tetracyanocomplex clathrates and their changes caused by heating were studied. The intermediates formed were characterized by IR and UV-VIS spectroscopy. Elemental analysis and XRD patterns were also used. For the visualisation of changes occurring on the surface and the distribution of metallic elements therein were studied by electron microscopy and EDX. The extent of the non-stoichiometric changes introduced by the topochemical course of the degradation reactions was correlated with the measured electrical values.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Bubanec, Dissertation, Chemical Faculty, Slovak Technical University, Bratislava 1986.

    Google Scholar 

  2. A. Sopková, J. Incl. Phenom., 14 (1992) 5.

    Article  Google Scholar 

  3. T. Nakano, T. Miyoshi, T. Iwamoto and Y. Sasaki, Bull. Chem. Soc. Japan, 40 (1967) 1297.

    Article  CAS  Google Scholar 

  4. T. Iwamoto, T. Miyoshi, T. Miyamoto and Y. Sasaki, Bull. Chem. Soc. Japan 40 (1967) 1174.

    Article  CAS  Google Scholar 

  5. T. Miyoshi, T. Iwamoto and Y. Sasaki, Inorg. Nucl. Chem. Let., 6 (1970) 21.

    Article  CAS  Google Scholar 

  6. J. Chomič, J. Černák, I. Potočňák, I. Zvereva and N. Savelieva, Chem. Papers, 47 (1993) 131.

    Google Scholar 

  7. S. Nishikiori and T. Iwamoto, Chem. Lett., 1129 (1983).

  8. T. Iwamoto, Isr. J. Chem., 18 (1979) 240.

    CAS  Google Scholar 

  9. T. Kitazava, M. Imamura, H. Yuge and T. Iwamoto, VI. International Symposium on Molecular Recognition and Inclusion, C-10, September 10–14, Berlin 1990.

  10. Ki-M. Park and T. Iwamoto, Incl. Phenom. Molec. Recogn. Chem., 11 (1991) 397.

    Article  CAS  Google Scholar 

  11. A. B. Dempster and H. Uslu, Spectrochim. Acta, 34A, 71 Pergamen Press 34A (1978) 71.

  12. S. Nishikiori, T. Iwamoto, C. I. Ratcliffe and J. A. Ripmeesrer, VI. International Symposium on Molecular Recognition and Inclusion, C-8, September 10–14, Berlin 1990.

  13. J. Bubanec, A. Sopková and G. Janák, J. Incl. Phenom., 17 (1994) 329.

    Article  CAS  Google Scholar 

  14. J. Bubanec, A. Sopková and G. Janák, Chem. Listy 84 (1990) 87.

    CAS  Google Scholar 

  15. A. Reller, H. R. Beer and H. R. Oswald, Experientia Suppl. 37, Birkhaaxer, Basel 1979.

    Google Scholar 

  16. A. Sopková, F. Kal'avsky, M. Singliar, J. Bubanec and P. Králik, Chem. Papers, 40 (1986) 735.

    Google Scholar 

  17. M. Šingliar, A. Sopková and J. Bubanec, Czechoslov. Appl. 251957.

  18. J. Bubanec and A. Sopková, J. Incl. Phenom. 6 (1988) 221.

    Article  CAS  Google Scholar 

  19. J. Bubanec, IV. Čs. konference: Methody připravy a charakterizace práškovych materiálů, VŠCHT, p. 97, 6–7. záfí, Pardubic, 1993.

  20. A. Sopková, Chem. Listy 79 (1985) 692.

    Google Scholar 

  21. J. Černák, M. Dunaj-Jurčo, M. Melník, J. Chomic and J. Skoršepa, Reviews in Inorganic Chemistry, Vol. 9, Nos. 2–3 (1988) 259.

    Google Scholar 

  22. M. Reháková and A. Sopková, Collection Czechoslovak Chem. Commun., Vol. 52, (1987) 2890.

    Article  Google Scholar 

  23. M. Imamura, T. Kitazavwa and T. Iwamoto, VI. International Symposium on Molecular Recognition and Inclusion, C-4, September 10–14, Berlin 1990.

  24. M. O. Clerk, S. B. Copp, S. Subramanian and M. J. Z. Zavratko, Superamoles. Chem. 1 (1992) 7.

    Article  CAS  Google Scholar 

  25. K. Seitz, Diploma Thesis, Philipps-Universität, Marburg 1986.

    Google Scholar 

  26. D. J. Cram and J. M. Cram, Container Molecules and their Guests, Royal Soc. Chem., Cambridge, 1994.

    Google Scholar 

  27. J. Bubanec, A. Sopková and M. Šingliar, VI. Intern. Symposium on Molecular Recognition and Inlcusion, C 17, Berlin, 1990.

  28. L. Stoch and I. Waclawská, J. Thermal Anal., 42 (1994) 99.

    Article  CAS  Google Scholar 

  29. A. Sopková, P. Mondík and M. Reháková, J. Thermal Anal. 47 (1996) 365.

    Article  Google Scholar 

  30. A. Sopková, P. Mondik and M. Reháková, ICTAC News, Vol. 26 (1995) 2.

    Google Scholar 

  31. M. Weber, Supramolecular Chemistry — Directed Synthesis and Molecular Recognition (Topics and Current Chemistry) Vol. 165, Springer Verlag, Berlin (1993).

    Google Scholar 

  32. A. K. Galwey, J. Thermal Anal., 42 (1994) 267.

    Article  Google Scholar 

  33. J. Bubanec and A. Sopková, prepared for J. Incl. Phenom.

  34. H. Nishimura, H. Kataoka and T. Miyauchi, Kagaku Kogaku 33 (1969) 181.

    Google Scholar 

  35. H. Nishimura and K. Morita, Japan Patent 57-157005, 1982.

Download references

Author information

Authors and Affiliations

  1. Department of Inorganic Chemistry, Faculty of Sciences, P. J. Safarik's University, 04154, Kosice, Slovak Republic

    J. Bubanec & A. Sopková

Authors
  1. J. Bubanec
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Sopková
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bubanec, J., Sopková, A. About the thermal decomposition of tetracyanocomplexes. Journal of Thermal Analysis 50, 831–841 (1997). https://doi.org/10.1007/BF01979213

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01979213

Keywords

Search

Navigation