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Synthesis, characterization, spectral and thermal properties of metal-hydrazinium nitrilotriacetates

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Abstract

Hydrazine derivatives of the monobasic nitrilotriacetate salts of zinc and alkaline earth metals have been prepared. IR absorption frequencies and thermal properties of these metal-hydrazinium nitrilotriacetates, (N2H5)M[N(CH2COO)3]·xH2O have been defined. All the three -COOH appear to be dissociated in these salts. In thermal decomposition, these salts initially undergo dehydration followed by dehydrazination and via acetate intermediate step to metal oxycarbonates.

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Author notes

  1. G. K. Naik

    Present address: Department of Chemsitry, S. P, Chowgule College, 403 602, Margao Goa, India

Authors and Affiliations

  1. Department of Chemistry, Goa University, Taleigao Plateau, 403 203, Goa, India

    J. S. Budkuley & G. K. Naik

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  1. J. S. Budkuley
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Budkuley, J.S., Naik, G.K. Synthesis, characterization, spectral and thermal properties of metal-hydrazinium nitrilotriacetates. Journal of Thermal Analysis 50, 815–821 (1997). https://doi.org/10.1007/BF01979211

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