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Organotin complexes of pyridine-2-carbothioamide

Summary

Complexes of pyridine-2-carbothioamide with diethyltin dichloride, dibenzyltin dichloride and phenyltin trichloride are described. In each case, the chelating agent is bound to the tin(IV) atom by the pyridine nitrogen and the carbothioamide sulphur, giving support to proposals that certain organotin compounds cause enzyme deactivation via the formation of tin-sulphur bonds.

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Literatur

  1. G.J. Sutton, Aust. J. Chem.22, 2475 (1969).

    CAS  Article  Google Scholar 

  2. G.J. Sutton, Aust. J. Chem.19, 2059 (1966).

    CAS  Article  Google Scholar 

  3. H.A. Goodwin, F.E. Smith, E. Konig and G. Ritter, Aust. J. Chem.26, 521 (1973).

    CAS  Article  Google Scholar 

  4. F.E. Smith and H.A. Goodwin, Proceedings of the XIX International Conference on Coordination Chemistry, Prague 1978.

  5. C.N.R. Rao and R. Venkataraghavan, Spectrochim. Acta18, 541 (1962).

    CAS  Article  Google Scholar 

  6. B. Siugh and K.P. Thakur, J. inorg. nucl. Chem.36, 1735 (1974).

    Article  Google Scholar 

  7. S. Ahrland, J. Chatt and N.R. Davies, Q. Rev. chem. Soc.12, 265 (1958).

    CAS  Article  Google Scholar 

  8. R.G. Pearson, J. Am. chem. Soc.85, 353 (1963).

    Article  Google Scholar 

  9. D. Calley, W.L. Guess and J. Autian, J. Pharm. Sci.56, 1267 (1967).

    CAS  Article  PubMed  Google Scholar 

  10. P. Karrer and J. Schukri, Helv. chim. Acta28, 824 (1945).

    CAS  Article  Google Scholar 

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Acknowledgment. We thank the Tin Industry (Research and Development) Board, Kuala Lumpur, for financial support.

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Smith, F.E., Ee, K.L. Organotin complexes of pyridine-2-carbothioamide. Experientia 36, 391–392 (1980). https://doi.org/10.1007/BF01975104

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  • DOI: https://doi.org/10.1007/BF01975104

Keywords

  • Free Amino Acid
  • Amino Acid Pool
  • Pyridine Nitrogen
  • Lower Wave Number
  • Haemin