Composition of hydrothermal fluids during the bradyseismic crisis which commenced at Phlegraean Fields in 1982

Abstract

A systematic geochemical surveillance on the fumaroles of Solfatara and the boiling pools of Pisciarelli was carried out by discontinuous monitoring of the chemical composition of the emitted fluids during the Phlegraean Fields bradyseismic crisis which has begun in 1982. The fluids are considered to be produced by the ebullition of shallow aquifers receiving a convective gaseous inflow from the underlying magma chamber.

Increased water vapor concentrations at a constant temperature of about 155 °C throughout the investigated period, along with the occurrence of ground deformations and seismic phenomena, are interpreted as resulting from an increased heat supply to the boiling water bodies.

Dissolution processes and reactions with the confining rocks can alter the chemical composition of fluids escaping from magma to a large extent. Therefore it does not appear correct to consider the absolute values of any chemical constituent for geochemical surveillance without taking this modifying factor into account. Acid gases will be preferably absorbed by the above mentioned aquifers, while other species like H₂, N₂, O₂, CH₄, will instead increase their relative concentrations. Because of this, water vapour concentrations and the ratios H₂S/CO₂ and H₂/CH₄ in surface thermal manifestations appear to reflect better the varying extent of the observed phenomenon.

On the basis of these parameters, and of both the upheaval rate and the intensity of seismic events, maximum values in the convective input of magmatic origin are estimated to have occurred at the beginning of the crisis and in September–October 1983.

As long as water bodies at shallow depth are able to buffer the convective flow both thermally and chemically, no important volcanic activity can develop. When the absorbing capacity of these aquifers is exhausted, the increasing temperature and the changing characteristics of fluids towards a magmatic composition will indicate a higher probability of eruptive phenomena.