Summary
Cadmium is present naturally in the air mainly as a result of volcanic emissions and release by vegetation. Anthropogenic sources, which overall give rise to emissions one order of magnitude greater than natural sources, are largely primary non-ferrous metals production and waste incineration. Measured concentrations of airborne cadmium are typically < 1 ng m−3 at remote sites, 0.1–10 ng m−3 at rural sites and 1–100 ng m−3 at urban and industrial sites, dependent upon the nature and proximity of local sources. Particle sizes are generally <2 μm, and often considerably smaller, consistent with an anthropogenic source and a long atmospheric life-time. Cadmium deposition to the land occurs with fluxes varying from 0.05 ng cm−2 month−1 in Greenland to circa 1000 ng cm−2 month−1 in the vicinity of major industrial sources. The possible significance of a motor vehicular source of airborne cadmium is also reviewed.
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References
Beauford, W., Barber, J., and Barringer, A.J. Release of particles containing metals from vegetation into the atmosphere. Science195 (1972) 571–573.
Biggins, P.D.E., and harrison, R.M., Atmospheric chemistry of automotive lead. Envir. Sci. Technol.13 (1979) 558–565.
Bloom, H., and Noller, B.N., Application of trace analysis techniques to the study of atmospheric metal particulates, in: Proceedings of a Symposium on Analytical Techniques for the Determination of Air Pollutants, pp. 98–111. Clean Air Society of Australia and New Zealand, 1977.
Boutron, C., Atmospheric trace metals in the snow layers deposited at the South Pole from 1928–1977. Atmos. Envir.16 (1982) 2451–2459.
Cadle, S.H., and Williams, R.L., Gas and particle emission from automobile tyres in laboratory and field studies. J. Air Pollut. Control. Assoc.28 (1978) 502–507.
Cameron, A.J., and Nickless, G., Use of mosses as collectors of airborne heavy metals near a smelting complex. Water, Air, Soil Pollut.7 (1977) 117–125.
Cawse, P.A., A survey of atmospheric trace elements in the U.K. (1972–73). United Kingdom Atomic energy Authority Report AERE-R7669. H.M.S.O., London 1974.
Cawse, P.A., and Peirson, D.H., An analytical study of trace elements in the atmospheric environment. United Kingdom Atomic Energy Authority Report AERE-R7134. H.M.S.O., London 1972.
Chamberlain, A.C., Aspects of the deposition of radioactive and other gases and particles. Int. J. Air Pollut.3 (1960) 63–68.
David, D.J., and Williams, C.H., Heavy metal contents of soils and plants adjacent to the Hume Highway near Marulan, New South Wales. Aus. J. exp. Agric. Anim. Husb.15 (1975). 414–418.
Davidson, C.I., Chu, L., Grimm, T.C., Nasta, A., and Qamoos, M.P., Wet and dry deposition of trace elements onto the Greenland ice sheet. Atmos. Envir.15 (1981) 1429–1437.
Department of the Environment, Cadmium in the environment and its significance to man. Pollution Paper No. 17. H.M.S.O., London 1980.
Donagi, A., Ganor, E., Shenhar, A., and Cember, H., Some metallic trace elements in the atmospheric aerosols of the Tel-Aviv urban area. J. Air Pollut. control. Assoc.29 (1979) 53–54.
Dorn, C.R., Pierce, J.O., Phillips, P.E., and Chase, G.R., Airborne Pb, Cd, Zn and Cu concentration by particle size near a Pb smelter. Atmos. Envir.10 (1976) 443–446.
Duce, R.A., Hoffman, G. L., Zoller, W. H., Atmospheric trace metals at remote Northern and Southern hemisphere sites. Science187 (1975) 59–61.
Duhameau, W., and Noël, R., Five years of recording the atmospheric fall-out in the industrial region of Liege, in: Atmospheric Pollution 1978, Proceedings of the 13th International Colloquium, Paris, France, pp. 29–32. Elsevier, Amsterdam 1978.
Eatough, D.J., Eatough, N.L., Hill, M.W., Mangelson, N.F., Ryder, J., and Hansen, L.D., The chemical composition of smelter flue dusts. Atmos. Envir.13 (1979) 489–506.
Faoro, R.B., and McMullen, T.B., National trends in trace metals in ambient air. Report No. 450/1-77-003. U.S. Environmental Protection Agency, 1977.
Feely, H.W., and Larsen R., Measurements of the chemical composition of wet, dry and total atmospheric deposition. Environmental Measurements Laboratory Report EML 347, pp. 7–20. U.S. Department of Energy, 1978.
First, M.W., Aerosols in nature. Archs. intern. Med.131 (1972) 24–32.
Fleischer, M., Sarofim, A.F., Fassett, D.W., Hammond, P., Shacklette, H.T., Nisbet, I.C.T., and Epstein, S., Environmental impact of cadmium, a review by the Panel on Hazardous Trace Substances. Envir. Hilth Perspect.7 (1974) 252–323.
Gaarenstroom, P.D., Perone, S.P., and Moyers, J.L., Application of pattern recognition and factor analysis for characterisation of atmospheric particulate composition in southwest desert atmosphere. Envir. Sci. Technol.11 (1977) 795–800.
Galloway, J.N., Eisenreich, S.I., and Scott, B.C., U.S. National Atmospheric Deposition Report No. NC-141. Dept. of Environmental Sciences, University of Virginia 1980.
Galloway, J.N., Thornton, J.D., Norton, S.A., Volchok, H.L., and McLean, R.A.N., Trace metals in atmospheric deposition: A review and assessment. Atmos. Envir.16 (1982) 1677–1700.
Gish, C.D. and Christensen, R.E., Cadmium, lead and zinc in earthworms from roadside soil. Envir. Sci. Technol.7 (1973) 1060–1062.
Hallet, J.P., Lardinois, P., Ronneau, C., and Cara, J., Elemental deposition as a function of distance from an industrial zone. Sci. total Envir.25 (1982) 99–109.
Harrison, R.M., Toxic metals in street and household dusts. Sci. total Envir.11 (1979) 89–97.
Harrison, R.M., and McCartney, H.A., Some measurements of ambient air quality at a coastal site in rural north-west England. Atmos. Envir.14 (1980) 233–244.
Harrison, R.M., Perry, R., and Wellings, R.A., Lead and cadmium in precipitation: their contribution to pollution. J. Air Pollut. Control. Assoc.25 (1975) 627–630.
Harrison, R.M., and Williams, C.R., Atmospheric cadmium pollution at rural and urban sites in north-west England, in: Proceedings of the International Conference, Management and Control of Heavy Metals in the Environment, pp. 262–266. CEP Consultants Ltd. London 1979.
Harrison, R.M., and williams, C.R., Characterisation of airborne heavy metals within a primary zinc-lead smelting works. Envir. Sci. Technol.15 (1981) 1197–1204.
Harrison, R.M. and Williams, C.R., Airborne cadmium, lead and zinc at rural and urban sites in North-west England. Atmos. Envir.16 (1982) 2669–2681.
Heinrichs, H., Trace element discharge from a brown coal fired power plant. Envir. Technol. Lett.3 (1982) 127–136.
Herron, M.M., Langway, C.C., Weiss, H.V., and Cragin, J.M., Atmospheric trace metals and sulphate in the Greenland ice sheet. Geochim. cosmochim. Acta4 (1977) 915–920.
Hiatt, V., and Huff, J.E., The environmental impact of cadmium: an overview. Int. J. envir. Stud.7 (1975) 277–285.
Hobbs, P.V., Radke, L.F., and Stith, J.L., Eruptions of the St. Augustine Volcano; airborne measurements and observations. Science195 (1977) 871–873.
Hopke, P.K., Lamb, R.E., and Natusch, D.F.S., Multielemental characterisation of urban roadway dust. Envir. Sci. Technol.14 (1980) 164–172.
Huttzicker, J.J. Friedlander, S.K., and Davidson, C.I., Air-Water-Land Relationships for Selected Pollutants, pp. 82–115. Final Report to the Rockefeller Foundation, USA, 1975.
Khandekar, R.N., Kelkar, D.N., and Vohra, K.G., Lead, cadmium, copper, zinc and iron in atmosphere of Greater Bombay, Atmos. Envir.14 (1980) 457–461.
Kleinman, M.T., Kneip, T.J., Bernstein, D.M., and Eisenbud, M., Fallout of toxic trace metals in New York City, in: Biological Implications of Metals in the Environment, CONF-740929, pp. 144–152. Energy Research and Development Administration. Washington D.C. 1977.
Lagerwerff, J.V., and Specht, A.W., Contamination of road-side soil with cadmium, nickel, lead and zinc. Envir. Sci. Technol.4 (1970) 583–586.
Lee, R.E., Caldwell, J., Akland, G.E., and Fankhauser, R., The distribution and transport of airborne particulate matter and inorganic components in Great Britain. Atmos. Envir.8 (1974) 1095–1109.
Lee, R.E., and Duffield, F.V. Sources of environmentally important metals in the atmosphere, in: Advances in Chemistry Series No. 172, Ultratrace Metal Analysis in Biological Sciences and Environment, ch. 11, pp. 146–171. American Chemical Society, 1979.
Lindberg, S.E., Factors influencing trace metal, sulphate and hydrogen ion concentration in rain. Atmos. Envir.16 (1982) 1701–1709.
Little, P., and Martin, M.H., A survey of zinc, lead and cadmium in soil and natural vegetation around a smelting complex. Envir. Pollut.3 (1972) 241–254.
Lum, K.R., Betteridge, J.S., and Macdonald, R.R., The potential availability of P, Al, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn in urban particulate matter. Envir. Technol. Lett.3, (1982) 57–62.
Mankovska, B., The content of Pb, Cd and Cl in forest trees caused by the traffic of motor vehicles. Biologia Bratisl.32 (1977) 477–489.
McDonald, C., and Duncan, H.J., Variability of atmospheric levels of metals in an industrial environment. J. envir. Sci. HlthA 13 (1978) 687–695.
McInnes, G., Multi-element survey: report on first year's results, Report No. LR277(AP). Warren Spring Laboratory, U.K. Department of Industry, 1978.
McInnes, G., Multi-element survey: report on second year's results, Report No. LR289(AP). Warrent Spring Laboratory, U.K. Department of Industry, 1978.
McInnes, G., Multi-element survey: analysis of the first two years' results. Report No. LR305(AP). Warren Spring Laboratory, U.K. Department of Industry, 1979.
Moyers, J.L., Ranweiler, L.E., Hopf, S.B., and Korte, N.E., Evaluation of particulate trace species in southwest desert atmosphere. Envir. Sci. Technol.11 (1977) 789–794.
Natusch, D.F.S., Wallace, J.R., and Evans, C.A., Toxic trace elements. Preferential concentration in respirable particles. Science183 (1974) 202–204.
Nriagu, J.O. Global inventory of natural and anthropogenic emissions of trace metals to the atmosphere. Nature279 (1979) 409–411.
Oakes, T.W., Furr, A.K., Adair, D.J., and Parkinson, T.F., Neutron activation analysis of automotive exhaust pollutants. J. radioanalyt. Chem.37 (1977) 881–888.
Ondov, J.M., Zoller, W.H., and Gordon, G.E., Trace metal emissions on aerosols from motor vehicles. Envir. Sci. Technol.16 (1982) 318–328.
Parry, G.D.R., Goodman, G.T., and Smith, S., A simple technique for the monitoring of airborne heavy metals prior to revegetation, in: Environmental Management of Mineral Wastes, pp. 273–295. Eds G.T. Goodman and M.J. Chadwick. Sijthoff and Noordhoff, Amsterdam 1978.
Prater, B.E., The environmental significance of cadmium in U.K. steelmaking operations. Envir. Technol. Lett.3 (1982) 179–192.
Roach, S.A. and Wakeley, R.W., Environmental control and hygiene at the Avonmouth zinc-lead smelter, in: Proceedings of a Symposium, Minerals and the Environment, pp. 505–513. Institution of Mining and Metallurgy, London 1975.
Ronneau, C., and Desaedeleer, G., Fall-out of pollutants from distant industrial areas in a rural environment. Paper IAEA-SM-206-11, in: Measurement Detection and Control of Environmental Pollutants, pp. 165–71. International Atomic Energy Agency, Vienna 1976.
Skogerboe, R.K., Dick, D.L., and Lamothe, P.J., Evaluation of filter inefficiencies under low loading conditions. Atmos. Envir.11 (1977) 243–259.
Smith, B.C., Coppock, B.W., Scott, T.C., and Firkin, G.R., Population control on an ISP complex in: Conference Proceedings, south Australia, pp. 277–287. Australasian Institute of Mining and Metallurgy, 1975.
Thrane, K.E., Background levels in air of lead, cadmium, mercury and some chlorinated hydrocarbons measured in south Norway. Atmos. Envir.12 (1978) 1155–1161.
Trindade, H.A., Pfeiffer, W.C., Londres, H., and Costa-Ribeiro, C.L., Atmospheric concentration of trace metals and total suspended particulates in Rio de Janeiro. Envir. Sci. Technol.15 (1981) 84–89.
Turner, A.C., The Midlands Metal Survey: Concentrations of 15 elements in the air around factories in Birmingham and the Black Country — Part 1, Report No. LR303(AP). Warren Spring Laboratory, U.K. Department of Industry, 1979.
Turner, A.C., and Killick, C.M., The Midlands Metal Survey: Concentrations of 15 elements in the air around factories in Birmingham and the Black Country — Part 2, Report No. LR304(AP). Warren Spring Laboratory, U.K. Department of Industry, 1979.
Ward, N.I., Brooks, R.R., Roberts, E., and Boswell, E., Heavy-metal pollution from automotive emissions and its effect on roadside soils and pasture species in New Zealand. Envir. Sci. Technol.11 (1977) 917–920.
Wilcox, S.L., Keitz, E.L., and Duncan, L.J. Establishing safe ambient air quality levels for eighteen hazardous pollutants, in: Recent Advances in the Assessment of the Health Effect of Environmental Pollution, vol. III, pp. 1241–1251. Commission of the European Communities, 1975.
Willeke, K., and Whitby, K.T., Atmospheric aerosols: size distribution interpretation. J. Air Pollut. Control. Assoc.25 (1975). 529–534.
Williams, C.R., Investigations into airborne cadmium, lead and zinc at rural urban and industrial sites. Ph. D. Thesis, University of Lancaster, Lancaster, U.K. 1981.
Wilson, D.C., Young, P.J., Hudson, B.C., and Baldwin, E., Leaching of cadmium from pigmented plastics at a landfill site. Envir. Sci. Technol.16 (1982) 560–566.
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Williams, C.R., Harrison, R.M. Cadmium in the atmosphere. Experientia 40, 29–36 (1984). https://doi.org/10.1007/BF01959099
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DOI: https://doi.org/10.1007/BF01959099