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The structure of three isomers of monodeacetylfusicoccin

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Riassunto

Si dimostra che tre metaboliti secondari diFusicoccum amygdali Del., presenti in piccola quantità nelle acque madri di cristallizzazione della fusicoccina, corrispondono a monodeacetilallofusicoccina (VI), monodeacetilisofusicoccina (VIII) e 12-O-acetil-dideacetilfusicoccina (X).

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Literatur

  1. A. Ballio, C. G. Casinovi, G. Randazzo andC. Rossi, Experientia26, 349 (1970).

    Google Scholar 

  2. A. Ballio, E. B. Chain, P. de Leo, B. F. Erlanger, M. Mauri andA. Tonolo, Nature, Lond.203, 297 (1964).

    Google Scholar 

  3. A. Ballio, M. Brufani, C. G. Casinovi, S. Cerrini, W. Fedeli, M. Pellicciari, B. Santurbano andA. Vaciago, Experientia24, 631 (1968).

    Google Scholar 

  4. K. D. Barrow, D. H. R. Barton, Sir ErnstChain, U. F. W. Ohnsorge andR. Thomas, J. chem. Soc. (C)1971, 1265.

  5. A. Ballio, C. G. Casinovi, M. Framondino, G. Grandolini, F. Menichini, G. Randazzo andC. Rossi, Experientia28, 126 (1972).

    Google Scholar 

  6. All acetylations were performed with acetic anhydride-pyridine at room temperature.

  7. NMR-spectra were recorded on a Varian HA-100 apparatus with TMS as internal reference. Optical rotations were measured with a Perkin-Elmer 141 polarimeter on ethanolic solutions. Mass spectra were recorded, on an AEI MS-902 spectrometer. Melting points are uncorrected. All compounds gave satisfactory elementary analyses.

  8. Catalytic hydrogenations were performed with Pd on BaSO4 at room temperature.

  9. This work was supported in part by the Italian National Research Council (CNR).

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Author notes

  1. G. Grandolini

    Present address: Istituto di Chimica Farmaceutica e Tossicologia, University of Perugia, Perugia, Italy

  2. C. Rossi

    Present address: Istituto di Tecnica e Legislazione Farmaceutica, University of Perugia, Perugia, Italy

Authors and Affiliations

  1. Laboratorio di Chimica delle Sostanze Naturali, Istituto di Chimica Organica dell'Università, I-80134, Napoli

    A. Ballio, C. G. Casinovi, M. Framondino, G. Grandolini, G. Randazzo & C. Rossi

  2. Laboratori di Chimica Biologica, Istituto Superiore di Sanità, Roma, (Italy)

    A. Ballio, C. G. Casinovi, M. Framondino, G. Grandolini, G. Randazzo & C. Rossi

Authors
  1. A. Ballio
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  2. C. G. Casinovi
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  3. M. Framondino
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  4. G. Grandolini
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  5. G. Randazzo
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  6. C. Rossi
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Ballio, A., Casinovi, C.G., Framondino, M. et al. The structure of three isomers of monodeacetylfusicoccin. Experientia 28, 1150–1151 (1972). https://doi.org/10.1007/BF01946137

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  • DOI: https://doi.org/10.1007/BF01946137

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