Experientia

, Volume 30, Issue 8, pp 844–845 | Cite as

19-Deoxydideacetylfusicoccin, a minor metabolite ofFusicoccum amygdali Del

  • A. Ballio
  • C. G. Casinovi
  • V. d'Alessio
  • G. Grandolini
  • G. Randazzo
  • C. Rossi
Chimica, Biochimica

Keywords

Alla Minor Metabolite Fusicoccina 

Riassunto

Un metabolita secondario diFusicoccum amygdali Del, presente in piccola quantità nelle acque madri di cristallizazione della fusicoccina, corrisponde alla 19-deossidideacetilfusicoccina. Il nuovo composto è stato anche ottenuto per sintesi a partire dalla dideacetilfusicoccina.

Literatur

  1. 1.
    A. Ballio, E. B. Chain, P. De Leo, B. F. Erlanger, M. Mauri andA. Tonolo, Nature, Lond.203, 297 (1964).Google Scholar
  2. 2.
    A. Ballio, M. Brufani, C. G. Casinovi, S. Cerrini, W. Fedeli, R. Pellicciari, B. Santurbano andA. Vaciago, Experientia24, 631 (1968).PubMedGoogle Scholar
  3. 3.
    K. D. Barrow, D. H. R. Barton, Sir Ernst Chain, U. F. W. Ohnsorge, andR. Thomas J. chem. Soc. (C)1971, 1265.Google Scholar
  4. 4.
    A. Ballio, C. G. Casinovi, G. Randazzo andC. Rossi, Experientia26, 349 (1970).PubMedGoogle Scholar
  5. 5.
    A. Ballio, C. G. Casinovi, M. Framondino, G. Grandolini, F. Menichini, G. Randazzo andC. Rossi, Experientia28, 126 (1972).PubMedGoogle Scholar
  6. 6.
    A. Ballio, C. G. Casinovi, M. Framondino, G. Grandolini, G. Randazzo andC. Rossi, Experientia28, 1150 (1972).PubMedGoogle Scholar
  7. 7.
    Two further derivatives containing 3 acetyl groups have been recently identified as 12-O-acetylfusicoccin and 12-O-acetylisofusicoccin (paper in preparation).Google Scholar
  8. 8.
    K. D. Barrow, D. H. R. Barton, Sir Ernst Chain, V. F. N. Ohnsorge andR. P. Sharma, J. chem. Soc. (Perkin I),1973, 1590.Google Scholar
  9. 9.
    K. D. Barrow, D. H. R. Barton, Sir Ernst Chain, C. Conlay, T. C. Smale, R. Thomas andE. S. Waight, J. chem. Soc. (C)1971, 1259.Google Scholar
  10. 10.
    This work was supported in part by the Italian Research Council (CNR).Google Scholar

Copyright information

© Birkhäuser Verlag 1974

Authors and Affiliations

  • A. Ballio
    • 1
    • 2
  • C. G. Casinovi
    • 1
    • 2
  • V. d'Alessio
    • 1
    • 2
  • G. Grandolini
    • 1
    • 2
  • G. Randazzo
    • 1
    • 2
  • C. Rossi
    • 1
    • 2
  1. 1.Istituto di Chimica Organica dell'UniversitàNapoli
  2. 2.Laboratori di Chimica BiologicaIstituto Superiore di SanitàRomaItaly

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