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Ion-solvent interaction: Viscosity, apparent molar volume and conductivity of univalent electrolytes in dioxanewater mixtures at different temperatures

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Summary

The viscosity, apparent molar volume and conductivity of NaCl, KCl, NaBr, KBr, NaNO3 and KNO3 solutions at mass fraction of dioxane (10, 20 and 30%)-water mixtures at 30–45°C±0.01°C have been measured. The ions appear to interact appreciably, and the ion-solvent interaction is of the order NO3 −>Br−>Cl−.

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References

  1. R. W. Gurney, in: Ionic Processes in Solutions, p. 159. McGraw Hill Co, New York 1953.

    Google Scholar 

  2. R. L. Kay, T. Vituccio and D. F. Evans, J. phys. Chem.70, 2336 (1966).

    Article  CAS  Google Scholar 

  3. P. Rastogi and R. Gopal, Z. phys. Chem.69, 1 (1970).

    Article  Google Scholar 

  4. W. Y. Wen and S. Saito, J. phys. Chem.68, 2639 (1964).

    Article  CAS  Google Scholar 

  5. J. Padova and I. Abrahamer, J. phys. Chem.71, 2112 (1967).

    Article  CAS  Google Scholar 

  6. D. F. Frank and T. Smith, Trans. Faraday Soc.63, 2586 (1967).

    Article  Google Scholar 

  7. R. G. Gopal, K. Singh and A. Siddique, Z. phys. Chem.75, 7 (1971).

    Article  CAS  Google Scholar 

  8. R. Gopal and K. Singh, Z. phys. Chem.69, 81 (1970).

    Article  CAS  Google Scholar 

  9. J. R. Ernesto and J. E. Lind, Jr, J. chem. Soc.1966, 2876.

  10. R. L. Kay and D. F. Evans, J. phys. Chem.70, 2974 (1968).

    Google Scholar 

  11. R. D. Singh and R. Gopal, Bull. chem. Soc. Jap.,45, 2088 (1972).

    Article  CAS  Google Scholar 

  12. W. A. Adams and K. J. Laidler, Can. J. Chem.46, 1977 (1968).

    Article  CAS  Google Scholar 

  13. M. A. V. Devanathan and M. J. Fernada, Trans. Faraday. Soc.56, 1409 (1960).

    Article  Google Scholar 

  14. R. M. Diamond, J. phys. Chem.67, 2513 (1967).

    Article  Google Scholar 

  15. W. Y. Wen, S. Saito and W. H. Lee, J. phys. Chem.70, 1254 (1970).

    Google Scholar 

  16. P. B. Das, Electro Chim. Acta, in press (1977).

  17. P. B. Das, P. K. Das and D. Patnaik, J. Ind. chem. Soc.36, 411 (1959).

    Google Scholar 

  18. R. H. Stokes and R. Mills, in: Viscosity and Related Properties, p. 124. Pergamon Press, New York 1965.

    Google Scholar 

  19. R. L. Kay, in: Adv. Chem. Series, p. 1, No. 73. R. F Gould, American Chemical Society, Washington D. C. 1968.

    Google Scholar 

  20. P. Assarson and F. R. Eirich, J. phys. Chem.72, 2710 (1968).

    Article  Google Scholar 

  21. R. L. Blokhra and Y. P. Sehgal, Ind. J. Chem.14A, 162 (1976).

    CAS  Google Scholar 

  22. D. K. Aggrawal and K. Singh, J. Ind. chem. Soc.53, 482 (1976).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Ravenshaw College, 753003, Cuttack, India

    N. C. Das & P. B. Das

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  1. N. C. Das
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  2. P. B. Das
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Das, N.C., Das, P.B. Ion-solvent interaction: Viscosity, apparent molar volume and conductivity of univalent electrolytes in dioxanewater mixtures at different temperatures. Experientia 34, 976–977 (1978). https://doi.org/10.1007/BF01915295

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  • DOI: https://doi.org/10.1007/BF01915295

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