Abstract
A large number of transition-metal picoline halides were prepared, and their thermal decompositions were investigated by TG, DTG, DTA and thermomicroscopy. The compounds were classified on the basis of their thermal properties and two possible mechanisms of thermal decomposition were established.
Zusammenfassung
Zahlreiche übergangsmetall-Picolin-Halide wurden dargestellt und deren thermische Zersetzung mittels TG, DTG, DTA und Thermomikroskopie untersucht. Die Verbindungen wurden nach ihren thermischen Eigenschaften klassifiziert, und zwei mögliche Mechanismen der thermischen Zersetzung sind angegeben.
РЕжУМЕ
пОлУЧЕН РАД кОМплЕкс ОВ пЕРЕхОДНых МЕтАлл ОВ с пИкОлИНыМИ, тЕРМИЧЕс кОЕ РАжлОжЕНИЕ кОтОРых ИжУЧЕНО МЕтО ДАМИ тг, ДтА, Дтг И тЕРМОМИкРОскОпИИ. кл АссИФИкАцИь сОЕДИНЕ НИИ пРОВЕДЕНА НА ОсНОВЕ И х тЕРМИЧЕскИх сВОИст В И УстАНОВлЕНО ДВА ВОжМ ОжНОгО МЕхАНИжМА тЕРМИЧЕскОгО РАжлОж ЕНИь.
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Liptay, G., Borbély-Kuszmann, A. & Nagy, G. Studies on transition-metal picoline complexes. Journal of Thermal Analysis 32, 91–96 (1987). https://doi.org/10.1007/BF01914551
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DOI: https://doi.org/10.1007/BF01914551