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Polymorphic transitions in the binary system lead fluorapatite [Pb10(PO4)6F2] - calcium fluorapatite [Ca10(PO4)6F2]

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Abstract

The phase diagram of the binary system lead fluorapatite [Pb10(PO4)6F2] - calcium fluorapatite [Ca10(PO4)6F2] was determined over the whole composition and temperature range. Special attention was paid to the polymorphic transitions of the initial compounds and their behaviour in the investigated system. The two apatites form continuous solid solutions. Examinations were performed by means of thermal, microscopic, X-ray and dilatometric analyses.

Zusammenfassung

Im gesamten Konzentrations- und Temperaturbereich wurde das Phasendiagramm des binären Systemes Bleifluorapatit Pb10(PO4)6F2 - Calciumapatit Ca10(PO4)6F2 aufgestellt. Besonderes Augenmerk wurde polymorphen Übergängen der Ausgangsverbindungen und ihrem Verhalten im untersuchten System geschenkt. Es konnte festgestellt werden, daß beide Apatite kontinuierliche Mischkristallphasen bilden. Die Untersuchungen basieren auf Thermo-, Röntgendiffraktions-, mikroskopischer und dilatometrischer Analyse.

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References

  1. J. Berak, H. Lis, Papers and reports of the VIIth Symposium Chemistry Inorganic Phosphorus Compounds, Wroclaw, September 1978, p. 333.

  2. J. Berak and H. Dabrowiecka, Polish J. Chem., 54 (1980) 137.

    Google Scholar 

  3. J. Berak and W.Szuszkiewicz, Papers and reports of the VIIIth Symposium Chemistry Inorganic Phosphorus Compounds, Wroclaw, September 1980, 383.

  4. A. F. Wells, Structural Inorganic Chemistry, Oxford University Press (1986) 374.

  5. J. Berak and H. Dabrowiecka, Polish J. Chem., 53 (1978) 2663.

    Google Scholar 

  6. J. Berak and W. Szuszkiewicz, Roczniki Chem., 51 (1977) 2403.

    Google Scholar 

  7. J. Berak and H. Dabrowiecka, Polish J. Chem., 56 (1982) 1223.

    Google Scholar 

  8. E. R. Kreidler and F. A. Hummel, Am. Miner., 55 (1970) 170.

    Google Scholar 

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Academy of Economics, Komandorska 118/120, 53345, Wroclaw, Poland

    H. Podsiadlo

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  1. H. Podsiadlo
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Additional information

The author would like to express her deep gratitude to Prof. J. Berak for his help and fruitful discussions, and Prof. T. Znamierowska for her useful suggestions.

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Podsiadlo, H. Polymorphic transitions in the binary system lead fluorapatite [Pb10(PO4)6F2] - calcium fluorapatite [Ca10(PO4)6F2]. Journal of Thermal Analysis 36, 569–575 (1990). https://doi.org/10.1007/BF01914510

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  • DOI: https://doi.org/10.1007/BF01914510

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