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Calorimetric study of adduct formation at 300 K between H2Os3(CO)10 and Lewis bases

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Abstract

The enthalpies of the reactions H2Os3(CO)10(I)+L=H2Os3(CO)10L(II),L=PR3, P(OR)3, in chloroform were determined by means of microcalorimetry. Satisfactory agreement was found between the basicity parameters and the measured reaction enthalpies. As concerns the kinetics, qualitative correlation of a thermokinetics parameter with the steric factor of the ligand was observed.

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  1. Istituto di Chimica Generale ed Inorganica, Facoltà di Farmacia, Università di Torino, Italy

    L. Stradella

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  1. L. Stradella
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Stradella, L. Calorimetric study of adduct formation at 300 K between H2Os3(CO)10 and Lewis bases. Journal of Thermal Analysis 31, 671–673 (1986). https://doi.org/10.1007/BF01914245

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  • DOI: https://doi.org/10.1007/BF01914245

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