Skip to main content
SpringerLink
Log in

The accuracy of determining the kinetics constants and the law of linear compensation

  • Short Communication
  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

In the light of the data obtained concerning copper oxidation kinetics, the law of linear compensation:E=E 0 + 2.303β logZ has been examined critically. By the use of different calculation techniques, the existence of a “compensation” dependence has been observed for different pairs of values of the activation energyE and the pre-exponential constantZ, obtained for the same set of experimental data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. J. M. Thomas andW. J. Thomas, Introduction to the Principles of Heterogenous Catalysis. Academic Press, New York-London 1967.

    Google Scholar 

  2. O. Exner, Collection Czech. Chem. Commun., 29 (1964) 1094.

    Article  CAS  Google Scholar 

  3. A. D.Blackadder and C.Hinshelwood, J. Chem. Soc., (1958) 2720.

  4. R. F. Brown, J. Org. Chem., 27 (1962) 3015.

    Article  CAS  Google Scholar 

  5. R. Deutsch, Estimation Theory, Prentice-Hall, Inc. New York 1965.

    Google Scholar 

  6. W. Volk, Applied Statistic for Engineeres, McGraw-Hill Inc., New York 1969.

    Google Scholar 

  7. P. Kofstad, High-Temperature Oxidation of Metals, John Wiley and Sons, Inc. New York-London-Sydney 1966.

    Google Scholar 

  8. C. D. Doyle, J. Appl. Polymer Sci., 6 (1962) 639.

    Article  CAS  Google Scholar 

  9. J.Norwisz, N.Hajduk, Biul. Inst. Met. Niezel., 13 (1978) in press.

  10. J.Norwisz, N.Hajduk, Biul. Inst. Met. Niezel., 13 (1978) in press.

Download references

Author information

Authors and Affiliations

  1. Institute of Non-Ferrous Metals, Gliwice, Poland

    J. Norwisz & J. Plewa

Authors
  1. J. Norwisz
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. Plewa
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Norwisz, J., Plewa, J. The accuracy of determining the kinetics constants and the law of linear compensation. Journal of Thermal Analysis 17, 549–553 (1979). https://doi.org/10.1007/BF01914045

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01914045

Keywords

Search

Navigation