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Classification of physico-chemical transformations in thermal analysis

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Abstract

In the present classification the different types of physicochemical transformations are dealt with which may be useful in studying different substances by the methods of thermal analysis. Equations were derived for describing the correlation between the thermodynamic characteristics and the parameters of the differential thermal analytical (DTA) peaks for two classes of physicochemical transformations.

All experiments were conducted on DTA-4 instruments constructed in the Baykov Institute of Metallurgy, the USSR Academy of Sciences.

Резюме

Проведена классифиа ция различных типов физико-химических пр евращений, которая может оказат ься удобной при иссле довании различных веществ ме тодом термического анализа. Получены мат ематические соотнош ения для двух классов физикох имических превращений, связыва ющие термодинамичес кие характеристики прев ращения с параметрами пикор Д ТА (дифференциальног о термического анализ а), Теоретические положения статьи под тверждены экспериме нтальными результатами. Все экс перименты проводились на устан овке ДТА — 4, созданной в Институте Металлургии им. А. А. Байкова АН СССР.

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References

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Maslenkov, S.B., Kobilkin, A.N. & Nikolaev, A.G. Classification of physico-chemical transformations in thermal analysis. Journal of Thermal Analysis 21, 101–111 (1981). https://doi.org/10.1007/BF01913704

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  • DOI: https://doi.org/10.1007/BF01913704

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