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Thermal decomposition of complexes of Co(II), Ni(II) and Zn(II) ions with thiosalicylic acid or ethylenediamine

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Abstract

The thermal decompositions of crystalline Co(II), Ni(II) and Zn(II) complexes with thiosalicylic acid or ethylenediamine were investigated via the respective thermal curves. On the basis of the decomposition temperatures, the following sequences of stabilities of the studied compounds have been proposed: 1. [Co(SR)]≤[Ni(SR)]<[Zn(SR)]; 2. [Zn(en)2](NO3)2·2H2O<[Co(en)2](NO3)2<[Ni(en)3](NO3)2.

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References

  1. J. Maslowska and J. Szmich, Proc 11th Conf. Coord. Chem., Smolenice (Czech.), 1987, p. 221.

  2. J. Maslowska and J. Szmich, Acta Univ. Lodziensis, Folia Chim., 1989, (in print).

  3. J. Szmich, Doctoral Thesis, Technical Univ., Lódz (1989).

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Authors and Affiliations

  1. Institute of General Food Chemistry, Technical University, Lódz, Poland

    J. Maslowska & J. Szmich

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  1. J. Maslowska
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  2. J. Szmich
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Maslowska, J., Szmich, J. Thermal decomposition of complexes of Co(II), Ni(II) and Zn(II) ions with thiosalicylic acid or ethylenediamine. Journal of Thermal Analysis 36, 2701–2706 (1990). https://doi.org/10.1007/BF01913664

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  • DOI: https://doi.org/10.1007/BF01913664

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