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Journal of thermal analysis

, Volume 32, Issue 5, pp 1471–1475 | Cite as

Compensation effect resulting from the use of mechanistic equations, and its physical significance

  • K. N. Somasekharan
  • V. Kalpagam
Article

Abstract

A compensation effect is observed in the activation parameters resulting from various mechanistic equations; theT computed from the slope of theE*vs InA plot matches the observed DTG peak.

Keywords

Polymer Physical Chemistry Inorganic Chemistry Activation Parameter Physical Significance 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Zusammenfassung

Bei den sich aus Gleichungen für verschiedene Mechanismen ergebenden Aktivierungsparametern wurde ein Kompensationseffekt beobachtet; der aus der Neigung der GeradenE* gegen InA berechneteT-Wert stimmt mit der Lage des beobachteten DTG-Peaks überein.

Резюме

Компенсационный эфф ект проявлялся в активационных парам етрах, полученных на основе различных мех анистических уравне ний. ВеличиныТ, вычисленные из нак лона графической зависим остиЕ*-lnA, хорошо согла суются с наблюдаетмыми пика ми ДТГ.

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Copyright information

© Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest 1987

Authors and Affiliations

  • K. N. Somasekharan
    • 1
  • V. Kalpagam
    • 1
  1. 1.Department of Inorganic and Physical ChemistryIndian Institute of ScienceBangaloreIndia

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