Abstract
Several zinc(II) complexes of tridentate dibasic salicylidene amino acids have been prepared and characterized. All of them possess dimeric pseudo-octahedral structures, which were established on the basis of thermogravimetric analysis and superimposable infrared spectra of these complexes with those of manganese(II), cobalt(II), nickel(II), and magnesium(II) complexes.
Zusammenfassung
Einige Zink(II)-komplexe von dreizähligen, dibasischen Salizylidenaminosäuren wurden dargestellt und beschrieben. Alle diese Komplexe besitzen eine pseudooktaedrische Dimerstruktur. Dies wurde mittels thermogravimetrischer Analyse und auf Grund der deckungsgleichen IR-Spektren dieser Komplexe mit denen von Mangan(II)-, Kobalt(II)-, Nickel(II)- und Magnesium(II)-Komplexen festgestellt.
Резюме
Получены и охарактер изованы несколько комплексов цинка с тр идентатными двухосновными салиц илиденаминокислота ми. Все комплексы обладают д имерной псевдооктаэдрическ ой структурой, устано вленной на основе термогравиме трического анализа и сопоставлением ИК сп ектров этих комплекс ов с таковыми для двухвал ентных марганца, кобальта, никеля и маг ния.
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The senior author (RKR) expresses his deep gratitude to Prof. R. L. Dutta, Department of Chemistry, Burdwan University, India, for valuable suggestions and discussions during the course of the work. He is also grateful to Dr. R. N. Banerjee of Jadavpur University and Dr. P. Banerjee of the Indian Association for the Cultivation of Science, Calcutta for laboratory and other facilities.
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Ray, R.K., Kauffman, G.B. Zinc(II) complexes of salicylidene amino acids. Journal of Thermal Analysis 35, 1603–1609 (1989). https://doi.org/10.1007/BF01912935
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DOI: https://doi.org/10.1007/BF01912935