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Structural and thermal analysis of silicon isothiocyanates complexes of Fe(III) and Mn(II)

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Abstract

New complexes of Fe(III) and Mn(II) with RxSi(NCS)4−x as ligands have been prepared and characterized. The structure of the new compounds are discussed on the basis of their spectroscopic (IR and UV-Vis), magnetic susceptibility and thermal data.

Zusammenfassung

Es wurden neue Fe(III)- und Mn(II)-Komplexe mit Liganden der Formel RxSi(NCS)4−x hergestellt und beschrieben. Bei der Diskussion der Struktur dieser neuen Verbindungen wurden spektroskopische (IR, UV), thermische Daten und Daten über die magnetische Suszeptibilität verwendet.

Резюме

Получены и охарактер изованы новые компле ксы трехвалентного желе за и двухвалентного марганца с лигандами RxSi(NCS)4−x. Структура новых соединений обсужден на основе их спектарьлных данных (ИК спектроскопия, абс орбционная спектроскопия в УФ-и в идимой области), данных по маг нитной восприимчиво сти и термических данных.

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Authors and Affiliations

  1. Dept. of General and Inorganic Chemistry, Aristotelian University, P.O. Box 135, 54006, Thessaloniki, Greece

    A. Syngollitou-Kourakou & I. Tossidis

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  1. A. Syngollitou-Kourakou
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  2. I. Tossidis
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Syngollitou-Kourakou, A., Tossidis, I. Structural and thermal analysis of silicon isothiocyanates complexes of Fe(III) and Mn(II). Journal of Thermal Analysis 35, 1433–1440 (1989). https://doi.org/10.1007/BF01912920

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  • DOI: https://doi.org/10.1007/BF01912920

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