Skip to main content
SpringerLink
Log in

Investigation of exchange reactions between alkaline earth metal oxides and some transition metal halides

  • Published:
Journal of Thermal Analysis Aims and scope Submit manuscript

Abstract

DTA and the simultaneous recording of electrical conductivity were applied for the investigation of exchange reactions between alkaline earth metal oxides and some lead, copper and nickel halides. Although the possibility of the gaseous phase is not excluded for the majority of the reactions investigated, it is either the appearance of a liquid phase or the polymorphous transformation of CaO that has the decisive effect on the interaction mechanism.

Résumé

Emploi simultané de l'ATD et de la mesure de la conductivité électrique pour étudier les réactions d'échange entre les oxydes des métaux alcalino-terreux et différents halogénures de plomb, cuivre et nickel. Bien que la possibilité d'une phase gazeuse ne soit pas exclue pour la majorité des réactions étudiées, l'effet décisif sur le mécanisme d'interaction est provoqué par la fusion ou par la transformation polymorphique de CaO.

Zusammenfassung

Differentialthermoanalyse und elektrische Leitfähigkeitsmessungen wurden gleichzeitig zur Untersuchung der Austauschreaktionen zwischen Alkalierdoxyden und Blei-, Kupfer- und Nickelhalogeniden angewandt. Obwohl die Möglichkeit einer Gasphase für die meisten dieser Reaktionen nicht ausgeschlossen werden kann, ist entweder die Schmelze oder die polymorphe Umwandlung des CaO entscheidend für den Interaktionsmechanismus verantwortlich.

Резюме

Методом ДТА и одновре менной регистрапии электропроводности пересмотрены реакции взаимодейст вия оксидов щелочноз емельных металлов с некоторым и галогенидами свинца, меди и никеля. Х отя возможность газо фазовой ступени и не исключен а для большинства изуч енных нами реакций, ре шающее влияние на механизм в заимодействия оказывают либо появл ение расплава, либо по лиморфное превращение СаО.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. A. Hedvall, Einführung in die Festkörperchemie, Vieweg, Braunschweig, 1952.

    Google Scholar 

  2. G. Tamman, Z. Anorg. Allg. Chem., 160 (1927) 101.

    Article  CAS  Google Scholar 

  3. J. A. Hedvall andG. Heuberger, Z. Anorg. Allg. Chem., 122 (1922) 181; 128 (1923) 1; 140 (124) 243.

    Article  CAS  Google Scholar 

  4. D. Balarew, Z. Anorg. Allg. Chem., 160 (1927) 92.

    Article  Google Scholar 

  5. M. E. Pozin andA. M. Ginstling, Zh. Prikl. Khim., XX 6 (1953) 561.

    Google Scholar 

  6. K. Hardel, Z. Anorg. Allg. Chem., 357 (1958) 3.

    Google Scholar 

  7. H. J. Borchardt andB. A. Thompson, J. Am. Chem. Soc., 81 (1959) 4182.

    Article  CAS  Google Scholar 

  8. H. J. Borchardt andB. A. Thompson, J. Am. Chem. Soc., 82 (1960) 355.

    Article  CAS  Google Scholar 

  9. L. G. Berg andN. P. Burmistrova, Zh. Neorg. Khim., 5, 3 (1960) 676.

    CAS  Google Scholar 

  10. N. G. Kluchnikov, Rukovodstvo po neorganicheskomu sintezu, Khimiya, Moscow, 1969, pp. 120, 232.

    Google Scholar 

  11. G. Brauer, Rukovodstvo po preparativnoi neorganicheskoi Khimii, Izdatelstvo Inostrannoi literatury, Moscow, 1956, p. 438.

    Google Scholar 

  12. M.Nehme and S.Teichner, Bull. Soc. Chim. France, 2 (1960).

  13. P. Seword, J. Am. Chem. Soc., 67 (1945) 1189.

    Article  Google Scholar 

  14. A. R. Ubbelohde, Plavlenie i krystallicheskiya struktura, “Mir”, Moscow, 1969, p. 178.

    Google Scholar 

  15. B. V. Subba Rao, D. S. Datar andAbde Ali, J. Sci. and Ind. Res., 20 (1961) 347.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. V. I. Uljanov-Lenin Order Banner Kazan State University, Kazan, USSR

    N. P. Burmistrova & R. G. Fitzeva

Authors
  1. N. P. Burmistrova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. G. Fitzeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Burmistrova, N.P., Fitzeva, R.G. Investigation of exchange reactions between alkaline earth metal oxides and some transition metal halides. Journal of Thermal Analysis 4, 161–168 (1972). https://doi.org/10.1007/BF01911925

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01911925

Keywords

Search

Navigation