Abstract
The evaluation of the relative kinetic stability of a sequence of compounds in thermal decomposition processes based solely on the start temperature of thermolysis may be incorrect, if the temperature range of the thermal decomposition includes an isokinetic point.
References
V. A. Logvinenko, O. V. Gegola andL. I. Myachina, J. Thermal Anal., 14 (1978) 265.
V. A.Logvinenko, O. V.Gegola, G. N.Chekhova and Yu. A.Dyadin, Conference on the kinetics and mechanism of chemical reactions in solids. Novosibirsk, 1977. Thesises of the papers (in Russian). Part 1. p. 150.
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Logvinenko, V.A., Gegola, O.V. Errors in the evaluation of the thermal (kinetic) stability of compounds by means of the start temperature of thermal decomposition in the presence of isokinetic points. Journal of Thermal Analysis 18, 539–540 (1980). https://doi.org/10.1007/BF01910235
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DOI: https://doi.org/10.1007/BF01910235