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Contribution to the formulation of a structural model by the determination of kinetic data

I. Dehydration of hexaoxytelluric acid

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Abstract

The processes involved in the isothermal dehydration of hexaoxytelluric acid, Te(OH)6, are studied and the kinetic equations and activation energies corresponding to these processes are determined. The results are in agreement with a previously proposed structural model.

Résumé

On a étudié les réactions qui interviennent lors de la déshydratation isotherme de l'acide hexaoxytellurique Te(OH)6 et déterminé les équations cinétiques ainsi que les énergies d'activation correspondantes. Les résultats sont en accord avec un modèle structural proposé préalablement.

Zusammenfassung

Die an der isothermen Dehydratisierung der Hexaoxytellursäure Te(OH)6 beteiligten Vorgänge wurden untersucht und die diesen Vorgängen entsprechenden kinetischen Gleichungen und Aktivierungsenergien bestimmt. Die Ergebnisse sind mit einem früher vorgeschlagenen strukturellen Modell in Übereinstimmung.

Резюме

Изучены процессы изо термической дегидратации гексао ксителлуровой кисло, ты, Те(ОН)6, б определены кинетические уравне ния и энергии активаций со ответствующих процессов. Результат ы согласуются с ранее предложенной структ урной моделью.

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References

  1. C. Pico, M. L. Veiga andE. Gutierrez Rios, An. Quím., 73 (1977) 816.

    Google Scholar 

  2. J. Rosicky, J. Loub andJ. Pavel, Z. Anorg. Allgem. Chem., 334 (1965) 312.

    Article  Google Scholar 

  3. O. N. Breusov, O. I. Borob'eva, N. A. Druz', T. V. Revzina andB. P. Soboliev, Izvest. Akad. Nauk. S. S. S. R. Neorg. Materialy, 2 (1966) 308.

    Google Scholar 

  4. J. C. J. Bart, A. Bossi, P. Perissinoto, A. Castellan andN. Giordano, J. Thermal Anal., 8 (1975) 313.

    Google Scholar 

  5. C. Pico, E. Gutierrez Puebla andE. Gutierrez Rios, An. Quím., 73 (1977) 951.

    Google Scholar 

  6. H. Siebert, Z. Anorg. Allgem. Chem., 301 (1959) 161.

    Article  Google Scholar 

  7. E. Sharp, J. Amer. Ceram. Soc., 8 (1963) 374.

    Google Scholar 

  8. D. A.Joung, Decomposition of Solids, Pergamon, 1966, p. 32.

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Pico, C., Jerez, A., Veiga, M.L. et al. Contribution to the formulation of a structural model by the determination of kinetic data. Journal of Thermal Analysis 15, 191–195 (1979). https://doi.org/10.1007/BF01903641

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  • DOI: https://doi.org/10.1007/BF01903641

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