Skip to main content
SpringerLink
Log in

Adsorption of51Cr(VI) on manganese dioxide from aqueous solution

  • Original Papers
  • Published:
Microchimica Acta Aims and scope Submit manuscript

Abstract

Sorption of51Cr(VI) by MnO2 has been studied as a function of pH and ionic concentration in the presence of certain added cations and anions. The findings are explained in the light of deprotonation/hydroxyl ion association reaction on oxide surface and its subsequent interaction with the tracer. Infrared spectroscopy has shown the chemical interaction of Cr(VI) on the surface of MnO2. The influence of certain interfering ions has been shown on the sorption of51Cr(VI) on MnO2 surface. An attempt has been made to concentrate traces of51Cr under optimum experimental conditions. The experimental observation shows that the activity sorbed under specified conditions can be recovered appreciably by leaching the pre-adsorbed carrier.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. M. Mikhail, N. Z. Misak,Int. J. Appl. Rad. Isot. 1988,39, 1121.

    Google Scholar 

  2. O. V. Singh, S. N. Tandon,Int. J. Appl. Rad. Isot. 1977,28, 701.

    Google Scholar 

  3. J. L. Gascon, M. T. Crespo, M. L. Acena,J. Radioanal. Nucl. Chem. 1990,139, 249.

    Google Scholar 

  4. M. J. Gray, M. A. Malati,J. Chem. Tech. Biotech. 1979,29, 135.

    Google Scholar 

  5. S. M. Hasany, M. A. Qureshi,J. Radioanal. Nucl. Chem. 1986,100, 307.

    Google Scholar 

  6. D. R. Dreesen, E. S. Gladney, et al.,Environ. Sci. Technol. 1977,11, 1017.

    Google Scholar 

  7. N. Heckerman, R. A. Powers,J. Phys. Chem. 1955,57, 139.

    Google Scholar 

  8. S. Music,J. Radioanal. Nucl. Chem. 1986,700, 185.

    Google Scholar 

  9. E. Browing, Chromium, in:Toxicity of Industrial Metals, 2nd Ed., Butterworths, London, 1969, Chapter 12.

    Google Scholar 

  10. N. L. Nemerow,Liquid Waste of Industry, Theories, Practice of Treatment, Addison-Wesley, Reading, MA. 1971, p. 145.

    Google Scholar 

  11. W. N. Grune,J. Water Poll. Control Fed. 1970,42, 1211.

    Google Scholar 

  12. G. B. Wentink, J. E. Eztel,J. Water Poll. Control Fed. 1972,44, 1561.

    Google Scholar 

  13. T. Hyashi, et al.,J. Metal Finish (Jap.) 1961,50, 314.

    Google Scholar 

  14. R. B. Grieves,Ion Flotation for Industrial Waste at Warsaw, Indiana Sewage Treatment Plant, Vol. 14, Proc. 14th Ind. Waste Conf, Purdue University, W. Lafayette, IN., 1965, p. 110.

    Google Scholar 

  15. C.-P. Huang, M.-H. Wu,J. Water Poll Control Fed. 1975,47, 2437.

    Google Scholar 

  16. S. P. Mishra, S. N. Singh,Int. J. Appl. Rad. Isot.1987,38, 541.

    Google Scholar 

  17. R. A. Griffin, A. K. Au, R. R. Frost,J. Environ. Sci. Health 1977,A12, 431; K. R. Tandon, T. P. Crisp, J. Ellis,Talanta 1984,31, 227.

    Google Scholar 

  18. S. M. Hasany, M. H. Chaudhary,J. Radioanal. Nucl. Chem. 1987,111, 199 (and references therein).

    Google Scholar 

  19. R. C. Weast,Handbook of Chemistry and Physics, 69th Ed., Chemical Rubber Company, Cleveland, 1988.

    Google Scholar 

  20. F. Paneth,Monatsh. 1913,34, 401; K. Fajans, T. Erdey-Gruz,Z. Physik. Chem. 1929,A144, 161.

    Google Scholar 

  21. O. Hahn,Applied Radiochemistry, Cornell University Press, Ithaca, 1936, pp. 67, 90.

    Google Scholar 

  22. A. C. Wahl, N. A. Bonner,Radioactivity Applied to Chemistry, Wiley, New York, 1951, p. 117.

    Google Scholar 

  23. S. Music, M. Ristic, M. Tonkovic,Z. Wasser-Abwasser-Forsch. 1986,19, 186.

    Google Scholar 

  24. M. L. Hair,Infrared Spectroscopy in Surface Chemistry, Marcel Dekker, New York, 1967.

    Google Scholar 

  25. Y. S. Chen, J. N. Butler, W. Stumm,J. Coll. Int. Sci. 1973,43, 421.

    Google Scholar 

  26. K. R. Kar, M. M. Bhutani,J. Sci. Ind. Res. 1961,20B, 344.

    Google Scholar 

  27. R. Schlogel, W. Jones,J. Chem. Soc. Dalton Trans. 1984, 1283.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology, Hauz Khas, 110016, New Delhi, India

    Madan Mohan Bhutani, Ajit Kumar Mitra & Ramesh Kumari

Authors
  1. Madan Mohan Bhutani
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ajit Kumar Mitra
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ramesh Kumari
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bhutani, M.M., Mitra, A.K. & Kumari, R. Adsorption of51Cr(VI) on manganese dioxide from aqueous solution. Mikrochim Acta 107, 19–26 (1992). https://doi.org/10.1007/BF01772349

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01772349

Key words

Search

Navigation