Amplification processes for small primary differences in the properties of enantiomers
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Differences in the free energy of enantiomers may have two principal reasons: 1. the result of a special arrangement of external fields, or 2. asymmetric interaction due to parity-non-conservation. The effects, in general, will be very small so that an amplification is necessary in order to make them measurable. In doing so, the main problem is not to find a process of high amplification potential, but a reliable one where the obtained enantiomeric resolution is really due to differences in their properties and not an artifact caused by uncontrolled experimental parameters. Well-known cascading processes have been examined under this aspect, and two new types of amplifying processes involving solid phases and especially designed for this purpose, are described.
Key wordsChemical Evolution Origin of Optical Activity Chemical Amplification Cascading Processes
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