Abstract
Density profiles for chemically reacting hard spheres near the crystalline surface of the graphite basal plane are investigated by using the integral equation approach. The dependence of the profiles on the density of the bulk fluid, the degree of dimerization and the fluid-solid interaction potential is studied. It is shown that the density profiles of this chemically reacting fluid near the crystalline surface exhibit new features, compared with the case of a hard sphere fluid near a structureless wall.
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References
Henderson D., Ed.: Fundamentals of Inhomogeneous Fluids, Marcel Decker, New York, 1992.
Nicholson D. and Parsonage N.P.: Computer Simulation and the Statistical Thermodynamics of Adsorption, Academic Press, New York, 1983.
Steele W.A.: Surface Sci.36 (1973) 317; The Interaction of Gases with Solid Surfaces, Pergamon Press, Oxford, 1974.
Andersen H.C.: J. Chem. Phys.59 (1973) 471.
Chandler D. and Pratt L.R.: J. Chem. Phys.65 (1976) 2925.
Pratt L.R. and Chandler D.: J. Chem. Phys.66 (1977) 147.
Høye J.S. and Olaussen K.: Physica A104 (1980) 435.
Cummings P.T. and Stell G.: Mol. Phys.51 (1984) 253;55 (1985) 33.
Cummings P.T. and Stell G.: Mol. Phys.60 (1987) 1315.
Lee S.H., Cummings P.T., and Stell G.: Mol. Phys.62 (1987) 65.
Stell G. and Zhou Y.: J. Chem. Phys.91 (1989) 3618.
Zhou Y. and Stell G.: J. Chem. Phys.96, xi (1992), 1504; 1507;98 (1993) 5777.
Wertheim M.S.: J. Stat. Phys.35 (1984) 19; 35;42 (1986) 459; 477.
Lee S.H., Rasaiah J.C., and Cummings P.T.: J. Chem. Phys.83 (1986) 317.
Rasaiah J.C. and Lee S.H.: J. Chem. Phys.83 (1985) 5870;83 (1985) 6396.
Rasaiah J.C. and Zhu J.: J. Chem. Phys.92 (1990) 7554.
Groot R.D.: J. Chem. Phys.97 (1992) 3537.
Smith W.R. and Triska B.: J. Chem. Phys.100 (1994) 3019.
Busch N.A., Wertheim M.S., Chiew Y.C., and Yarmush M.L.: J. Chem. Phys.101 (1994) 3147.
Madden W.G.: J. Chem. Phys.96 (1992) 5422.
Madden W.G. and Glandt E.D.: J. Stat. Phys.51 (1988) 537.
Vega C., Kaminsky R.D., and Monson P.A.: J. Chem. Phys.99 (1993) 3003.
Rosinberg M.L., Tarjus G., and Stell G.: J. Chem. Phys.100 (1994) 5172.
Pizio O., Sokołowski S., and Henderson D.: J. Phys. Chem.99 (1995) 2408.
Pizio O., Sokołowski S., and Henderson D.: J. Coll. Interface Sci. (in press, 1995).
Pizio O., Sokołowski S., and Henderson D.: Mol. Phys. (in press, 1995).
Sokołowski S., Henderson D., and Pizio O.: J. Chem. Phys.102 (1995) 9048.
Baxter R.J.: J. Chem. Phys.49 (1968) 2770.
Kalyuzhnyi Yu.V., Stell G., Leano-Restrepo M.L., Chapman W.G., and Holovko M.F.: J. Chem. Phys.101 (1994) 7939.
Grundke E.W. and Henderson D.: Mol. Phys.24 (1972) 269.
Henderson D. and Grundke E.W.: J. Chem. Phys.63 (1975) 601.
Sokołowski S.: J. Chem. Soc. Faraday Trans. II78 (1982) 243.
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The authors wish to express gratitude to the CONACYT of México (Grant No. 4186-E9405 and el Fondo para Cátedras Patrimoniales de Excelencia) for financial support of the project. S.S. thanks KBN for partial financial support (Grant No. 2P30307705). We would like to express our thanks to A. Malijevsky for valuable discussions and comments. O.P. is grateful to C. Lozada Garcia for helpful discussions.
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Sokołowski, S., Henderson, D. & Pizio, O. Density profiles of a chemically reacting fluid adsorbed on the graphite basal plane. Czech J Phys 46, 67–83 (1996). https://doi.org/10.1007/BF01692242
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DOI: https://doi.org/10.1007/BF01692242