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Solubility of divalent zinc in natrium chloride crystals

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Cechoslovackij fiziceskij zurnal B Aims and scope

Abstract

The temperature dependence of the solubility of divalent zinc in natrium chloride crystals in a temperature range of 350 to 770°C has been determined by the method of diffusion saturation. The dependence has a retrograde character with a maximum of 5.10−4 molar fraction of Zn++ at 700°C. In the range of temperatures lower than 650°C the experimental results may be well expressed by the relationship

$$C_T = 0 \cdot 132\exp \left( { - \frac{{0 \cdot 458{\text{ }}eV}}{{kT}}} \right)$$

It has been shown that the reported experimental procedure makes it possible to prepare NaCl + + ZnCl2 samples with zinc concentration within the range of 2.10−5 5.10−4 molar fractions.

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Authors and Affiliations

  1. Institute of Physics, Slov. Acad. Sci., Dúbravská cesta, Bratislava

    V. Paulíny-Tóthová & I. Popeliš

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  1. V. Paulíny-Tóthová
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  2. I. Popeliš
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The authors gratefully acknowledge the help of J. Jesenská in performing the measurements.

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Paulíny-Tóthová, V., Popeliš, I. Solubility of divalent zinc in natrium chloride crystals. Czech J Phys 15, 921–928 (1965). https://doi.org/10.1007/BF01688675

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