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Isolation and identification of polychlorinated styrenes in Great Lakes fish

Summary

Octachlorostyrene was prepared by two independent synthetic routes, and GC retention time data as well as a mass spectrum of the standard were obtained. A comparison of these data with those observed for a component in fish from Lake Huron, Lake Ontario, and the lower Detroit River indicates that octachlorostyrene is present in fish residues from these sources. In addition, mass spectral data indicated the presence of several hepta and hexachlorostyrene isomers in these fish. Further studies should be concerned with quantification of OCS and evaluation of possible sources of these compounds, such as impurities in products produced by exhaustive chlorination or as by-products in the electrolytic production of chlorine.

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References

  1. BALLESTER, M., and J. CASTANER: J. Am. Chem. Soc.82, 4259 (1960).

    Article  CAS  Google Scholar 

  2. BALLESTER, M., C. MOLINET, and J. CASTANER: J. Am. Chem. Soc.82, 4254 (1960).

    Article  CAS  Google Scholar 

  3. BERG, O. W., P. L. DIOSADY, and G. A. V. REES: Bull. Environ. Contam. Toxicol.1, 338 (1972).

    Article  Google Scholar 

  4. KOEMAN, J. H., M. C. ten NOEVER de BRAUW, and R. H. DE VOSS: Nature221, 1126 (1969).

    Article  CAS  Google Scholar 

  5. KUEHI, D. W., G. E. GLASS, and G. D. VEITH: Paper presented at 22nd Annual Meeting of the American Society for Mass Spectrometry, May, 1974a.

  6. KUEHL, D. W., G. E. GLASS, and F. A. PUGLISI: Anal. Chem.46, 804 (1974b).

    Article  CAS  Google Scholar 

  7. SEIBER, J. N.: J. Org. Chem.36, 2001 (1971).

    Article  Google Scholar 

  8. ten NOEVER de BRAUW, M. C. and J. H. KOEMAN: Sci. Total Environ.1, 427 (1972/73).

    Article  Google Scholar 

  9. THOMPSON, J. F., ed.: Analysis of Pesticide Residues in Human and Environmental Samples. Prepared by Pesticides and Toxic Substances Effects Lab., U.S. Environmental Protection Agency, National Environmental Research Center, Research Triangle Park, North Carolina. Section4, A, (5,6). Revised December 1974.

    Google Scholar 

  10. VEITH, G. D., D. W. KUEHL, and J. ROSENTHAL: J. Assoc. Off. Anal. Chem.58, 1 (1975).

    CAS  Google Scholar 

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Kuehl, D.W., Kopperman, H.L., Veith, G.D. et al. Isolation and identification of polychlorinated styrenes in Great Lakes fish. Bull. Environ. Contam. Toxicol. 16, 127–132 (1976). https://doi.org/10.1007/BF01685217

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Keywords

  • Aldrin
  • Sandwich Tern
  • Fish Extract
  • Chlorocarbon
  • Great Lake Fish