Abstract
The crystal and molecular structure of a clip containing molecule is described. The structure was solved by vector search methods and refined by least squares methods toR l=0.0768 [I>2σ(I)]. Crystal data: C40H30N4O2·HCCl3, triclinic, space group\(P\bar 1\),a=9.302(2),b=12.981(2),c=15.765(2)Å, α=65.91(2)°, β=76.40(2)°, γ=80.15(1)°,V=1682.9(4)Å3, Z=2.
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Coolen, H.K.A.C.; van Leeuwen, P.W.N.M.; Nolte, R.J.M.Angewante. Chem. 1992,31, 905.
Coolen, H.K.A.C.; van Leeuwen, P.W.N.M.; Nolte, R.J.M.JACS 1995,117, 11906.
Reek, J.N.H.; Elemans, J.A.A.W.; Rowan, A.W.; Nolte, R.J.M.Submitted to JOC.
Sijbesma, R.P.; Kentgens, A.P.M.; Lutz, E.T.G.; van der Maas, J.H.; Nolte, R.J.M.J. Am. Chem. Soc. 1993,115, 8999.
Gosling, P.A.;Recl. Trav. Chim. Pays-bas. 1993,112, 404.
North, A.C.T.; Philips, D.C.; Matthews, F.S.Acta Crystallogr. 1968,A24, 351.
Sijbesma, R.P.; Bosman, W.P.; Nolte, R.J.M.J. Chem. Soc. Commun.1991, 885.
Beurskens, P.T.; Beurskens, G.; Strumpel, M.; Nordman, C.E.Patterson and Pattersons; Clarendon Press: Oxford, 1987; pp. 356–367.
Beurskens, P.T.; Admiraal, G.; Beurskens, G.; Bosman, W.P.; Garciá-Granda, S.; Gould, R.O.; Smits, J.M.M.; Smykalla, C.The DIRDIF program system: Technical Report of the Crystallography Laboratory; University of Nijmegen: The Netherlands, 1992.
Sheldrick, C.M.SHELXL-93: Program for the refinement of crystal structures; University of Göttingen: Germany, 1993.
International Tables for X-ray Crystallography Vol. IV, Kynoch Press: Birmingham, UK, 1974; pp. 99, 149.
Spek, A.L.ORTEP part of PLATON.13
Motherwell, W.D.S.GEOM: A program for Geometrical Calculation; University of Cambridge: England, 1976.
Spek, A.L.Acta Crystallogr. 1990,A46, C34.
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Bosman, W.P., Smits, J.M.M., de Gelder, R. et al. The crystal and molecular structure of 6,8,15,16b,16c,17-hexahydro-16b,16c-diphenyl-7H,16H-6a,7a,15a,16a-tetraazanaphtho[5,6]azulano[2,1,8-ij]naptho[f]azulene-7,16-dione. J Chem Crystallogr 26, 365–368 (1996). https://doi.org/10.1007/BF01677102
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DOI: https://doi.org/10.1007/BF01677102