Skip to main content
SpringerLink
Log in

Solid-state formation of an inclusion compound of cholic acid withp-toluidine

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Cholic acid undergoes solid-solid reactions with some aromatic molecules to form inclusion compounds. Simple shaking of a mixture of powdered cholic acid andp-toluidine results in formation of the 1∶1 (host:guest) inclusion compound which has the same structure as that formed by conventional crystallization methods: monoclinic space groupP21 witha=13.577(4),b=8.078(2),c=14.182(6) Å, β=114.42(3)°,Z=2 andR 1=0.061 for 2680 unique reflections.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Toda, F.; Tanaka, K.; Sekikawa, A.J. Chem. Soc., Chem. Commun. 1987, 279.

  2. Bond, D.R.; Johnson, L.; Nassimbeni, L.R.; Toda, F.J. Solid State Chem. 1991,92, 68.

    Google Scholar 

  3. Toda, F.; Yagi, M.; Kiyoshige, K.J. Chem. Soc., Chem. Commun. 1988, 958.

  4. Toda, F.; Shigemasa, T.;Carbohydr. Res. 1989,192, 363.

    Google Scholar 

  5. Toda, F.; Takumi, H.; Yamaguchi, H.Chem. Expr. 1989,4, 507.

    Google Scholar 

  6. Nakano, K.; Sada, K.; Miyata, M.Chem. Lett. 1994, 137.

  7. Miki, K.; Masui, A.; Kasai, N.; Miyata, M.; Sibakami, M.; Takemoto, K.J. Am. Chem. Soc. 1988,110, 6594.

    Google Scholar 

  8. Scott, J.L.Supramol. Chem. 1995; Submitted for publication

  9. Caira, M.R.; Nassimbeni, L.R.; Scott, J.L.Mol. Cryst. Liq. Cryst. 1995, in press.

  10. Scott, J.L.Supramol. Chem. 1995, Submitted.

  11. Caira, M.R.; Nassimbeni, L.R.; Scott, J.L.J. Chem. Soc. Chem. Commun. 1993, 612.

  12. Yvon, K.; W. Jeitschko and E. Parthé,J. Appl. Cryst. 1977,10, 73.

    Google Scholar 

  13. Sheldrick, G.M.SHELXS-86 Crystallographic Computing, Sheldrick, G.M.; Kruger, C.; Goddard, R. Eds.; Oxford University Press, 1985, Vol. 3, 175.

  14. Sheldrick, G.M.SHELXL-93: A Program for Crystal Structure Determination. J. Appl. Crystallogr. 1993, in preparation.

  15. Flack, H.D.; Schwarzenbach, D.Acta Crystallogr 1988,A44, 499.

    Google Scholar 

  16. Bertinotti, A.C.R. Acad. Sci. 1963,257, 4174.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Cape Town, 7700, Rondebosch, South Africa

    Janet L. Scott

Authors
  1. Janet L. Scott
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Scott, J.L. Solid-state formation of an inclusion compound of cholic acid withp-toluidine. J Chem Crystallogr 26, 185–189 (1996). https://doi.org/10.1007/BF01673668

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01673668

Key Words

Search

Navigation