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Crystal and molecular structure of 6-0-acetylgrayanotoxin III

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Abstract

The crystal and molecular structure of a grayanotoxin III derivative, 6-0-acetylgrayanotoxin III is presented. The crystal is orthorhombic, space group P212121, witha=15.582(3),b=21.304(3),c=6.339(3)Å,V=2104(1) Å3 Z=4. The structure was solved by direct methods and refined by full matrix least-squares methods to a finalR=0.047 for 1763 independent reflections withF 0>3 σ (F 0) The molecule is based on a tetracyclic structure consisting of two five-membered, one six-membered, and one seven-membered ring with various conformations.

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Authors and Affiliations

  1. Institute for Protein Research, Osaka University, 3-2 Yamadaoka, 565, Suita, Osaka, Japan

    Mamoru Sato & Yukiteru Katsube

  2. Department of Applied Chemistry, Osaka Institute of Technology, Omiya 5-16-1, Asahi-ku, 535, Osaka, Japan

    Masaaki Katai

  3. Facultyof Pharmaceutical Sciences, Setsunan University, 573-01, Hirakata, Osaka, Japan

    Jun' ichi Katakawa & Tadahiro Tetsumi

Authors
  1. Mamoru Sato
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  2. Yukiteru Katsube
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  3. Masaaki Katai
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  4. Jun' ichi Katakawa
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  5. Tadahiro Tetsumi
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Sato, M., Katsube, Y., Katai, M. et al. Crystal and molecular structure of 6-0-acetylgrayanotoxin III. J Chem Crystallogr 26, 153–156 (1996). https://doi.org/10.1007/BF01669733

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  • DOI: https://doi.org/10.1007/BF01669733

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