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Crystal structure ofcis-[Ru(bpy)2{PPh2(o-tol)}Cl][ClO4]·1.5(CH2Cl2), a structure containing both ordered and disordered dichloromethane molecules of crystallization

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Abstract

The complexcis-[Ru(bpy)2 {PPh2(o-tol)}Cl][ClO4] crystallizes from dichloromethane as the sesqui-dichloromethane solvate. The complex crystallizes in the monoclinic space group P21/n with Z=4. The structure was refined toR=5.50% for those 2552 independent reflections with |F 0|>6σ(|F 0|) The octahedral Ru(II) cation is associated with the following bond lengths: Ru-PPh2(o-tol)=2.360(3)Å. Ru−Cl=2.433(2)Å and Ru−N(bpy)=2.041(8)–2.095(8)Å. Both the perchlorate anion and the dichloromethane molecules of solvation exhibit large amplitudes of vibration. One dichloromethane molecule lies in a general position, the other lies about an inversion center and suffers from disorder.

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References

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Authors and Affiliations

  1. Department of Chemistry, Natural Sciences & Mathematics Complex, University at Buffalo, State University of New York, North Campus, 14260-3000, Buffalo, New York

    Melvyn Rowen Churchill, Lynn M. Krajkowski, My Hang Vo Huynh & Kenneth J. Takeuchi

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  1. Melvyn Rowen Churchill
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  2. Lynn M. Krajkowski
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  3. My Hang Vo Huynh
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  4. Kenneth J. Takeuchi
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Churchill, M.R., Krajkowski, L.M., Vo Huynh, M.H. et al. Crystal structure ofcis-[Ru(bpy)2{PPh2(o-tol)}Cl][ClO4]·1.5(CH2Cl2), a structure containing both ordered and disordered dichloromethane molecules of crystallization. J Chem Crystallogr 26, 111–116 (1996). https://doi.org/10.1007/BF01669726

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  • DOI: https://doi.org/10.1007/BF01669726

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