Abstract
The crystal and molecular structure of [(tBu)2Al(μ-NHtBu)]2 has been determined. The unit cell contains two independent molecules with only slight variation in the orientation of thetert-butyl ligands. Crystal data: Triclinic,\(P\bar 1\),a=9.0138(6),b=10.2944(8),c=15.791(1) Å, α=91.262(6), β=89.822(6), γ=106.141(6)°,V=1407.2(2) Å3,Z=2,R=0.039,R w=0.041.
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Davidson, N.; Brown, H.C.J. Am. Chem. Soc. 1942,64, 316.
For a recent review see, Robinson, G.H. In:Coordination Chemistry of Aluminum; Robinson, G.H., Ed.; VCH: New York, 1993; Chapter 2.
See, for example Bartke, T.C.; Haaland, A.; Novak, D.P.Acta Chem. Scand. 1975,29, 273.
Robinson, G.H.; Sangokoya, S.A.; Rogers, R.D.Polyhedron 1988,7, 2727.
Waggoner, K.M.; Power, P.P.:J. Am. Chem. Soc. 1991,113, 3385.
Lee, B.; Pennington, W.T.; Robinson, G.H.Inorg. Chim. Acta 1991,190, 173.
Choquette, D.M.; Timm, M.J.; Hobbs, J.L.; Rahim, M.M.; Ahmed, K.J.; Planalp, R.P.Organometallics 1992,11, 529.
Taghiof, M.; Hendershot, D.G.; Barbaer, M.; Oliver, J.P.J. Organomet. Chem. 1992,431, 271.
Byers, J.J.; Lee, B.; Pennington, W.T.; Robinson, G.H.Polyhedron,1992,11, 967.
Davidson, M.G.; Elilio, D.; Less, S.L.; Martin, A.; Raithby, P.R.; Snaith, R.; Wright, D.S.Organometallics 1993,12, 1.
Atwood, D.A.; Rutherford, D.Organometallics 1996,15, 436, and references therein.
See for example, Gosling, K.; McLaughlin, G.M.; Sim, G.A.; Smith, J.D.J. Chem. Soc. Chem. Commun. 1970, 1617.
McLaughlin, G.M.; Sim, G.A.; Smith, J.D.J. Chem. Soc. A. 1972, 2197.
Rogers, J.H.; Apblett, A.W.; Cleaver, W.M.; Tyler, A.N.; Barron, A.R.J. Chem. Soc. Dalton Trans. 1992, 3179.
Cleaver W.M.; Barron, A.R.Organometallics 1993,12, 1001.
Cleaver, W.M.; Barron, A.R.; McGufey, A.R.; Bott, S.G.Polyhedron 1994,13, 2831.
Bethley, C.E.; Aitken, C.L.; Koide, Y.; Harlan, C.J.; Bott, S.G.; Barron, A.R.,Organometallics, in press.
Mason, M.R.; Smith, J.M.; Bott, S.G.; Barron, A.R.J. Am. Chem. Soc. 1993,115, 4971.
SIR-Burla, M.C.; Camalli, M.; Cascarano, G.; Giacovazzo, C.; Polidori, G.; Spagna, R.; Viterbo, D.J. Appl. Cryst. 1989,22, 389.
MolEN-Enraf-Nonius. MolEN, An interactive Structure Solution Procedure; Enraf-Nonius, Delft, Netherlands,1990.
International Tables for X-Ray Crystallography; Kynoch Press: Birmingham, 1974; Vol. 4.
Barry, S.T.; Richeson, D.S.J. Organomet. Chem. 1996,510, 103.
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Bott, S.G., Koide, Y. & Barron, A.R. Molecular structure of [(tBu)2Al(μ-NHtBu)]2 . J Chem Crystallogr 26, 563–567 (1996). https://doi.org/10.1007/BF01668416
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DOI: https://doi.org/10.1007/BF01668416