Abstract
The reaction of [Ph3PAgI]4 with sodium phenylacetate in MeOH and CH2Cl2 at room temperature gave rise to a binuclear silver complex with triphenylphosphine and phenylacetate mixed ligands, [Ph3PAg(O2CCH2Ph)]2. The crystal and molecular structure of the complex has been determined by single crystal X-ray diffraction analysis. The space group is\(P\bar 1\) witha=9.198(2),b=9.516(2),c=13.842(3) Å, α=102.00(3), β=108.34(3), γ=93.58(3)°,Z=1, andDc=1.506 g cm−3. The silver atoms are each coordinated by one phosphorus atom from triphenylphosphine and two oxygen atoms from the carboxylate groups in a T-shape. The complex is further characterized by its IR,1H, and31P NMR spectra.
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Chen, X.M.; Mak, T.C.W.Polyhedron 1991,10, 1723.
Chen, X.M.; Mak, T.C.W.J. Chem. Soc. Dalton Trans. 1991, 1219.
Huang, W.Y.; Lu, L.; Chen, X.M.; Mak, T.C.W.Polyhedron 1991,10, 2687.
Mak, T.C.W.; Yip, W.H.; Chen, X.M.Inorg. Chim. Acta 1993,203, 97.
Chen, X.M.; Mak, T.C.W.J. Chem. Soc. Dalton Trans. 1991, 3253.
Sparks, R.A. InCrystallographic Computing Techniques; Ahmed, F.R., Ed.; Munksgaard: Copenhagen, Demmark, 1976.
Sheldrick, G.M. InComputational Crystallography; Sayre, D., Ed.; Oxford University Press; New York, 1982, pp 505
Sheldrick, G.M. InComputational Computing 3, Data Collection, Structural Determination, Proteins and Databases; Sheldrick, G.M.; Kreuger, C.; Goddard R., Eds.; Oxford. University Press: New York, 1985; pp 175.
International Tables for X-ray Crystallography; Kynoch Press: Birmingham, England, 1974; Vol. 4.
Diamond, R.Acta Crystallogr.Sect. A 1969,27, 43.
Teo, B.K.; Calabresi, J.C.Inorg. Chem. 1976,15, 10.
Pauling, L.The Nature of The Chemical Bond (third edition); Cornell University Press: Ithaca, New York, 1960; pp 85–90.
Stein, R.A.; Knobler, C.Inorg. Chem. 1977,16, 242.
Howatson, J.; Morosin, B.Cryst. Struct. Commun. 1973,2, 51.
Deacon, G.B.; Phillips, R.J.Coord. Chem. Rev. 1980,33, 227.
Antonius, F.M.J.; Van der Ploeg, A.F.M.J.; Van Koten, G.; Spek, A.L.Inorg. Chem. 1979,18, 1052.
Whitcomb, D.R.; Rogers, R.D.J.;J. Chem. Cryst. 1995,25, 137.
Neo, S.P.; Zhou, Z.Y.; Mak, T.C.W.; Hor T.S.A.Inorg. Chem. 1995,34, 520.
Cotton, F.A.; Wilkinson, G.Advanced Inorganic Chemistry (third edition); Wiley: New York, 1972; pp 1056.
Griffin, R.G.; Ellett, J.D. Jr; Mehring, M.; Bullitt, J.G.; Waugh, J.S.J. Chem. Phys. 1972,57, 2147.
Hong, M.C.; Mak, T.C.W. Submitted for publication.
Gorenstein, D.G.; Stah, D.O.3 slP NMR principles and applications: Academic Press: New York, 1984; p 55.
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Hong, MC., Mak, T.C.W., Zhou, ZY. et al. Structure of a binuclear silver(I) complex [Ph3PAg(O2CCH2Ph)]2 . J Chem Crystallogr 26, 553–557 (1996). https://doi.org/10.1007/BF01668414
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DOI: https://doi.org/10.1007/BF01668414